Answer:
A is the answer the reason why is because I got it right when I was doing my test
Which quantum state (n,ℓ,mℓ) is NOT possible? and why
2,0,0
3,1,-1
3,0,1
3,2,2
16,14,15
The quantum numbers that are not possible are 16,14,15.
What are quantum numbers?The quantum numbers are used to address the position of the electron in an atom. They are the set of numbers that show the most probable position of the electron in an atom. There are four sets of quantum numbers that describe the position of an electron and they are;
1) Principal quantum number
2) Orbital quantum number
3) Magnetic quantum number
4) Spin quantum number.
The set of quantum numbers 16,14,15 is not possible because ml must have values of -l to +l as we know.
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c55h72mdn4o5 what is the molar mass
If we sum the molar masses of the elements, we find that the molar mass of the compound C₅₅H₇₂N₄O₅ is 869.31 g/mol.
What is the molar mass?The molar mass is the mass in grams of 1 mole of a substance.
To calculate the molar mass of a compound, we need to sum the molar masses of the elements that form it, which can be found in the periodic table.
M(C₅₅H₇₂N₄O₅) = 55 M(C) + 72 M(H) + 4 M(N) + 5 (O)
M(C₅₅H₇₂N₄O₅) = 55 (12.01 g/mol) + 72 (1.01 g/mol) + 4 (14.01 g/mol) + 5 (16.00 g/mol) = 869.31 g/mol
There is a mistake in the question. The original question is:
C₅₅H₇₂N₄O₅, what is the molar mass?
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You are stowing items and come across an aerosol bottle of hairspray. What should you do? Please choose all that apply
Answer:stow the hairspray
Explanation:
Ammonium phosphate is an important ingredient in many solid fertilizers. It can be made by reacting aqueous phosphoric acid with liquid ammonia. Calculate the moles of ammonia needed to produce of ammonium phosphate. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.
Answer:
The balanced chemical equation:
3 NH₃ + H₃PO₄ → (NH₄)₃PO₄
From the equation we see:
3 moles of NH₃ gives 1 mole (NH₄)₃PO₄
0.085 mole NH₃ will gives ?? mole (NH₄)₃PO₄
By cross multiplication:
number of moles of (NH₄)₃PO₄ = 0.085 * 1/3 = 0.028 mole
Explanation:
738.90 m has ____ significant figures
Answer: 4
Explanation: because the zero doesn't count
47. If the molar mass of X(HCO3)2 is 162 g mol-¹, determine the relative atomic mass of X. [H=1.0, C = 12.0. O = 16.0] A. B. C. D. 40 48 61 101 please answer with step by step solution
Answer:
X(HCO3)2 is X2(C2H2O6), so the total number of atoms for each element can be calculated:
2 X atoms
4 H atoms
6 C atoms
12 O atoms
Calculate the total atomic mass of the elements:
2 X atoms * atomic mass of X = 2X * atomic mass of X
4 H atoms * 1.0 amu = 4.0 amu
6 C atoms * 12.0 amu = 72.0 amu
12 O atoms * 16.0 amu = 192.0 amu
The molar mass of X(HCO3)2 is 162 g/mol, so the total atomic mass of the elements should add up to 162 g/mol:
2X * atomic mass of X + 4.0 amu + 72.0 amu + 192.0 amu = 162 g/mol
Solve for X by rearranging the equation:
2X * atomic mass of X = 162 g/mol - 4.0 amu - 72.0 amu - 192.0 amu = -12.0 amu
2X = -12.0 amu / atomic mass of X
Divide both sides by 2:
X = -6.0 amu / atomic mass of X
So the relative atomic mass of X is 6.0 amu.
Guysss how to explain nuclear chemistry? And define nuclear chemistry ?
Answer:
How do amoeba respire.
Define Diffusion.
CuI2 (light brown solid) name copper compounds
CuI2 is not a known compound. Copper compounds typically have different oxidation states for copper, resulting in various compound names.
Copper(II) oxide (CuO): It is a black solid compound where copper is in the +2 oxidation state. It is commonly used as a pigment and in catalytic reactions.
Copper(II) sulfate (CuSO4): It is a blue crystalline compound in which copper is in the +2 oxidation state. It is used in various applications such as agriculture, electroplating, and as a laboratory reagent.
Copper(I) oxide (Cu2O): It is a red crystalline compound in which copper is in the +1 oxidation state. It is used as a pigment, in solar cells, and as a catalyst.
Copper(II) chloride (CuCl2): It is a greenish-brown solid compound in which copper is in the +2 oxidation state. It is utilized in various chemical processes, including etching and catalyst synthesis.
Copper(II) nitrate (Cu(NO3)2): It is a blue crystalline compound where copper is in the +2 oxidation state. It is commonly used in the production of catalysts, as a coloring agent, and in electroplating.
These are just a few examples of copper compounds with different oxidation states and properties. It's important to note that the compound CuI2 mentioned in the question, if it exists, would be an exception to the typical nomenclature for copper compounds.
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name one benifit and one limitation of comparative investigations
Answer:
Limitation of comparative investigation is that when it is done on a huge population, huge amount cost is required. Explanation: Benefit of comparative investigation is that we can get descrete information about specific breed or species. It is important for the study of behaviour of many organisms.
Explanation:
Sợ sánh kỹ thuật trích ly rắn lỏng với kỹ thuật trích ly lỏng
lỏng
Answer:
which language is this please tell me
Which part of the brain is affected by a smell, a song, or a photograph?
A. the primitive brain
B. the right brain
C. the outer brain
D. the emotional brain
The right brain part of the brain is affected by a smell, a song, or a photograph.
What is Right Brain?The right brain is more intuitive and visually oriented. It is occasionally referred to as the analog brain. It thinks less logically and with more creativity. According to out-of-date research by Sperry, the right brain aids in creativity.
Which part of brain deals with photograph?Posterior parietal cortex of the parietal lobe of the brain mainly deals with the photographs.
Which part of brain deals with Smell?The olfactory bulb, a structure in the front of the brain, processes smells before sending data to other regions of the body's central nervous system.
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The right brain part of the brain is affected by a smell, a song, or a photograph.
What is Right Brain?
The right brain is more intuitive and visually oriented. It is occasionally referred to as the analog brain. It thinks less logically and with more creativity. According to out-of-date research by Sperry, the right brain aids in creativity.
Which part of brain deals with photograph?
Posterior parietal cortex of the parietal lobe of the brain mainly deals with the photographs.
Which part of brain deals with Smell?
The olfactory bulb, a structure in the front of the brain, processes smells before sending data to other regions of the body's central nervous system.
The standard emf for the cell using the overall cell reaction below is =2.20 V:
2Al(s) + 3I2(s) ? 2Al3+ (aq) + 6I- (aq)
The emf (voltage) generated by the cell when [Al3+] = 4.0 x 10-3 M and [I-] = 0.015 M
is_______ V
The cell produces an emf of 2.32 V. For this cell reaction at 25 degrees Celsius, use the Nernst equation. where n represents the number of electrons exchanged during the cellular process.
What is the typical EMF this cell produces?According to measurements, the electromotive force (EMF) is 1.100 V. The standard condition is specified as a concentration of 1 M in an ideal solution, and as a result, 1.100 V is the standard electromotive force, DEo, or standard cell potential for the Zn–Cu galvanic cell.
How is the average Ecell determined?Due to the larger standard reduction potential of the silver half-cell, the reduction will occur. The half-cell of tin will oxidize. The formula E0cell=E0red+E0oxid can be used to get the overall cell potential.
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Which ion could bond with a calcium ion Which ion could bond with a calcium ion (Ca2+) to form a neutral ionic compound?
A. Cl-
B. NO3-
C. Mg2+
D. S2-(Ca2+)
The ion that could bond with a calcium ion (Ca2+) to form a neutral ionic compound is option A. Cl-.
This is because the calcium ion has a +2 charge, and the chloride ion (Cl-) has a -1 charge. When these two ions bond together, they form the compound CaCl2, which has a net charge of zero and is therefore neutral.
In order for an ionic compound to be neutral, the charges of the ions must cancel each other out. Therefore, the calcium ion needs to bond with an ion that has a -2 charge in order to form a neutral compound. The chloride ion is the only ion listed that has a -1 charge, and therefore it is the only one that can bond with the calcium ion to form a neutral compound.
So the correct answer is option A. Cl-.
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If 10.0 g of MgSO4⋅7H2O is thoroughly heated, what mass of anhydrous magnesium sulfate will remain?
If 10.0 g of MgSO4⋅7H2O is thoroughly heated, the mass of anhydrous magnesium sulfate will remain is 4.88 grams.
What is mass?Mass is the unit that quantify the matter in a physical body.
The molar mass of the MgSO4⋅7H2O is 246.47 grams.
When magnesium sulfate is heated, the molar mass of magnesium sulfate become 120.36 g/mol
Now, both molar masses are divide and multiplied by 10
\(\dfrac{120.36 g/mol}{246.47} \times 10 = 4.88 g.\)
Thus, the mass of anhydrous magnesium sulfate will remain is 4.88 grams.
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How much heat must be added to a 34.2 g sample of aluminum in order to raise the temperature of the aluminum 34 oC? (The specific heat of Aluminum is 0.9 J/g oC)
The amount of heat required to raise the temperature of the 34.2 g sample of aluminum by 34 oC is 1043.52 J.
What is Temperature?
Temperature is a measure of the average kinetic energy of the particles in a substance. It is a physical property that determines the direction of heat flow between two objects or systems in contact with each other. Temperature is measured in degrees Celsius (°C) or Fahrenheit (°F), or in kelvin (K) in the International System of Units (SI).
The amount of heat (q) required to raise the temperature of a substance can be calculated using the formula:
q = m x c x ΔT
Where:
m = mass of the substance (in grams)
c = specific heat of the substance (in J/g oC)
ΔT = change in temperature (in oC)
Plugging in the values given:
m = 34.2 g
c = 0.9 J/g oC
ΔT = 34 oC
q = (34.2 g) x (0.9 J/g oC) x (34 oC)
q = 1043.52 J
Therefore, the amount of heat required to raise the temperature of the 34.2 g sample of aluminum by 34 oC is 1043.52 J.
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Connor turns on a hair dryer to style his hair in the morning. Which choice identifies all of the energy transformations in the system?
electrical -- heat sound, and motion
electrical -- sound and motion
heat-electrical and sound
heat and sound -motion
Answer:
It is electrical → heat, sound, and motion
because a hair dryer makes heat to dry your hair and sound is the blowing and motion is how it goes
Explanation:
Answer:
A
Explanation:
electrical -- heat sound, and motion
Ammonia is among the top ten synthesized compounds. Its many uses include the manufacture of ammonium nitrate and other fertilizers. Ammonia decomposes at high temperatures. In an experiment to explore this behavior, 2.00 moles of gaseous NH3 are sealed in a rigid 1-liter vessel. The vessel is heated at 800 K and some of the NH3 decomposes in the following reaction:
2 NH3 (g) <-> N2 (g) + 3 H2 (g)The system eventualky reaches equilibrium and is found to contain 1.740 mole of NH3. What are the values of Kp and Kc for the decomposition reaction at 800k?
Answer:
Kc = 2.55x10⁻³
Kp = 10.97
Explanation:
Based on the reaction:
2 NH₃(g) ⇄ N₂(g) + 3H₂(g)
2 moles of ammonia produce 1 mole of nitrogen and 3 of hydrogen.
Kc is defined as:
Kc = [N₂] [H₂]³ / [NH₃]²
When 2.00 moles of NH₃ are added in a vessel and the reaction occurs, when the reaction is in equilibrium the moles of each specie is:
NH₃: 2.00moles - 2X
N₂: X
H₂: 3X
Where X represents reaction coordinate.
As moles in equilibrium of NH₃ are 1.740moles:
1.740 mol = 2.00 - 2X
0.13moles = X
That means moles of N₂ are 0.13 and H₂ 0.39
Replacing in Kc formula:
Kc = [0.13] [0.39]³ / [1.74]²
Kc = 2.55x10⁻³To obtain Kp from Kc you need to use the formula:
Kp = Kc (RT)^Δn
Where R is 0.082atmL/molK, T is temperature in Kelvin (800K) and Δn is change in moles of gas, that is moles of products - moles of reactants ( 4 - 2 = 2)
Replacing:
Kp = 2.55x10⁻³(0.082atmL/molKₓ800K)²7
Kp = 10.97
The values of Kp and Kc for the decomposition reaction of ammonia at 800k is 2.5 × 10⁻³ and 10.97 respectively.
What is Kp and Kc?Kp and Kc both are equilibrium constants with respect to the partial pressure and concentration in molaity respectively.
Given chemical reaction with ICE table will be represented as:
2 NH₃(g) ⇄ N₂(g) + 3H₂(g)
Initial: 2 0 0
Change: -2x +x +3x
Equilibrium: 2-2x x 3x
According to the question moles of NH₃ at equilibrium is 1.740 mol, so
2 - 2x = 1.740 mol
x = 0.13moles
Kc equation for the given reaction is:
Kc = [N₂].[H₂]³ / [NH₃]²
Kc = (x).(3x)³ / (0.13)²
Kc = 2.5 × 10⁻³
Kp will be calculated as:
Kp = Kc.(RT)ⁿ, where
R = universal gas constant = 0.082atmL/mol.K
T = temperature = 800K
n = change in moles = 4 -2 = 2
Kp = (2.5 × 10⁻³)[(0.082)(800)]²
Kp = 10.97.
Hence value of Kp & Kc is 2.5 × 10⁻³ and 10.97 respectively.
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7.00 of Compound x with molecular formula C3H4 are burned in a constant-pressure calorimeter containing 35.00kg of water at 25c. The temperature of the water is observed to rise by 2.316c. (You may assume all the heat released by the reaction is absorbed by the water, and none by the calorimeter itself.) Calculate the standard heat of formation of Compound x at 25c.
Be sure your answer has a unit symbol, if necessary, and round it to 3 significant digits.
Answer:
\(\Delta H_{f,C_3H_4}=276.8kJ/mol\)
Explanation:
Hello!
In this case, since the equation we use to model the heat exchange into the calorimeter and compute the heat of reaction is:
\(\Delta H_{rxn} =- m_wC_w\Delta T\)
We plug in the mass of water, temperature change and specific heat to obtain:
\(\Delta H_{rxn} =- (35000g)(4.184\frac{J}{g\°C} )(2.316\°C)\\\\\Delta H_{rxn}=-339.16kJ\)
Now, this enthalpy of reaction corresponds to the combustion of propyne:
\(C_3H_4+4O_2\rightarrow 3CO_2+2H_2O\)
Whose enthalpy change involves the enthalpies of formation of propyne, carbon dioxide and water, considering that of propyne is the target:
\(\Delta H_{rxn}=3\Delta H_{f,CO_2}+2\Delta H_{f,H_2O}-\Delta H_{f,C_3H_4}\)
However, the enthalpy of reaction should be expressed in kJ per moles of C3H4, so we divide by the appropriate moles in 7.00 g of this compound:
\(\Delta H_{rxn} =-339.16kJ*\frac{1}{7.00g}*\frac{40.06g}{1mol}=-1940.9kJ/mol\)
Now, we solve for the enthalpy of formation of C3H4 as shown below:
\(\Delta H_{f,C_3H_4}=3\Delta H_{f,CO_2}+2\Delta H_{f,H_2O}-\Delta H_{rxn}\)
So we plug in to obtain (enthalpies of formation of CO2 and H2O are found on NIST data base):
\(\Delta H_{f,C_3H_4}=3(-393.5kJ/mol)+2(-241.8kJ/mol)-(-1940.9kJ/mol)\\\\\Delta H_{f,C_3H_4}=276.8kJ/mol\)
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Consider 5.00 L of a gas at 365 mmHg and 20. ∘C . If the container is compressed to 2.30 L and the temperature is increased to 40. ∘C , what is the new pressure, P2, inside the container? Assume no change in the amount of gas inside the cylinder.
Answer:
P₂ = 1.12 atm
Explanation:
To find the new pressure, you need to use the Combined Gas Law:
\(\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}\)
In this equation, "P₁", "V₁", and "T₁" represent the initial pressure, volume, and temperature. "P₂", "V₂", and "T₂" represent the new pressure, volume, and temperature. Before plugging the values into the equation, you need to
(1) convert the pressure from mmHg to atm (760 mmHg = 1 atm)
(2) convert the temperatures from Celsius to Kelvin (°C + 273)
The final answer should have 3 sig figs like the given values.
P₁ = 365 mmHg / 760 = 0.480 atm P₂ = ? atm
V₁ = 5.00 L V₂ = 2.30 L
T₁ = 20°C + 273 = 293 K T₂ = 40°C + 273 = 313 K
\(\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}\) <----- Combined Gas Law
\(\frac{(0.480 atm)(5.00 L)}{293 K}=\frac{P_2(2.30 L)}{313 K}\) <----- Insert values
\(0.00819=\frac{P_2(2.30 L)}{313 K}\) <----- Simplify left side
\(2.56 = P_2(2.30L)\) <----- Multiply both sides by 313
\(1.12 = P_2\) <----- Divide both sides by 2.30
In the equation 2Li2O(s)=O2(g)+4L(i)
We heat 25g of Li2O until no more oxygen is produced.
q) How many L of oxygen is expected to be produced.
In the given equation 5.96 L of O2 will be produced.
What is chemical equation?
A chemical equation is a symbolic representation of a chemical reaction that shows the reactants on the left side and the products on the right side, with the coefficients indicating the relative amounts of each substance involved. It follows the law of conservation of mass, which states that mass cannot be created or destroyed in a chemical reaction.
The balanced equation for the reaction is:
2Li₂O(s) → O₂(g) + 4Li(s)
From the equation, we can see that 2 moles of Li₂O produces 1 mole of O₂. We can use this ratio to convert the mass of Li₂O to moles of O₂
First, we need to calculate the number of moles of Li₂O:
n(Li₂O) = m/M
where m is the mass of Li₂O and M is the molar mass of Li₂O. The molar mass of Li₂O is:
M(Li₂O) = 2(M(Li) + M(O)) = 2(6.941 g/mol + 15.999 g/mol) = 45.88 g/mol
Plugging in the values, we get:
n(Li₂O) = 25 g / 45.88 g/mol = 0.544 mol
According to the balanced equation, 2 moles of Li₂O produce 1 mole of O2. So, the number of moles of O2 produced is:
n(O2) = 0.544 mol / 2 = 0.272 mol
Finally, we can convert the number of moles of O2 to liters using the ideal gas law:
PV = nRT
where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature. Assuming the reaction occurs at standard temperature and pressure (STP), which is 0°C (273.15 K) and 1 atm, we can simplify the equation to:
V = nRT/P
Plugging in the values, we get:
V = (0.272 mol) (0.08206 L·atm/mol·K) (273.15 K) / 1 atm = 5.96 L
Therefore, we can expect 5.96 L of O2 to be produced.
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find the volume of a gas at standard pressure if its volume at 1.9 atm is 80 ml?
given:
formula:
substitution:
answer:
Answer:
1.5 × 10² mL
Explanation:
Step 1: Given data
Initial pressure of the gas (P₁): 1.9 atmInitial volume of the gas (V₁): 80 mLFinal pressure of the gas (P₂): 1.0 atm (standard pressure)Final volume of the gas (V₂): ?Step 2: Calculate the final volume of the gas
For an ideal gas, we can calculate the final volume of the gas using Boyle's law.
P₁ × V₁ = P₂ × V₂
V₂ = P₁ × V₁/P₂
V₂ = 1.9 atm × 80 mL/1.0 atm
V₂ = 1.5 × 10² mL
Since the pressure decreased, the volume of the gas increased.
what is a nuclear acid
Answer:
Nucleic acid is an important class of macromolecules found in all cells and viruses. Deoxyribonucleic acid (DNA) encodes the information the cell needs to make proteins.
A related type of nucleic acid, called ribonucleic acid (RNA), comes in different molecular forms that participate in protein synthesis.
According the equation: 2H,O+ electricity → 2H2 + O2
A) An electrolytic cell, because it absorbs energy.
B) A voltaic cell, because it releases energy. C) A voltaic cell, because it absorbs
energy.
D) An electrolytic cell, because it releases energy.
E) All of them
Answer:
A) An electrolytic cell, because it absorbs energy.
Explanation:
The major difference between an electrolytic cell and a voltaic cell is that, in an electrolytic cell, there must be input of energy from outside (a cell) to drive the non spontaneous reaction while in a voltaic cell, the reaction proceeds on its own and releases energy which could be harnessed to do work.
Hence, considering the equation; 2H2O+ electricity → 2H2 + O2 , energy is supplied as electricity in order for the process to take place. This is an example of an electrolytic cell.
Lab Report: Paper Chromatography
As the questions when you are the same this assignment to your acher by the clear
Describe generally what happened beach set of ik had the messigments
Tube where
2. Came the sceness of each of the sens
3. has the of the unknown Use or your chim
You are gen an unknowne of thing. How could you use the procedures in this to see this dye
Virtual Lab Active Step 4: Measuring the Volume of Air Near 0°C Measure the height of the column of gas in the tube. (Click the ruler and capillary tube.) Temperature of gas: Intro °C 600 ml F 600 500 400 00 200 100 Height of the column of gas: 20 10 cm DONE
From the attached image, the volume of the air column is 300 mL and the temperature of the gas is 3°C.
What is the relationship between the temperature and the volume of a given mass of air?The relationship between the temperature and the volume of a given mass of air is described by the gas law known as Charles's law. According to this law, the volume of a fixed amount of gas (such as air) held at constant pressure is directly proportional to its absolute temperature (measured in Kelvin). In other words, as the temperature of the air increases, its volume will also increase, and vice versa.
Mathematically, Charles's law can be expressed as:
V ∝ T
where V is the volume of the gas, T is its absolute temperature, and the symbol "∝" means "is proportional to".
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Which type of solution is one with a pH of 8?acidicneutralbasic
Explanation:
The following image describes the pH scale:
Between 0 and 7 we have an acidic solution, 7 is a neutral solution, and a solution with pH between 7 and 14 is a basic solution.
Answer: basic
Someone plz hello me ASAP it would be appreciated on question 9 btw
Answer:
C.
Explanation:
The water is being stored for the time being, and potential energy is, essentially, defined like that. Once the energy is utilized, it will turn into kinetic energy.
What is the median reaction of second end point in HCL and NaOH titration
The median reaction at the second end point in the HCl and NaOH titration is: HCl + NaOH → NaCl + H2O
In a titration between hydrochloric acid (HCl) and sodium hydroxide (NaOH), the reaction involved is the neutralization reaction between an acid and a base. The balanced equation for this reaction is:
HCl + NaOH → NaCl + H2O
In this reaction, one mole of HCl reacts with one mole of NaOH to form one mole of NaCl (sodium chloride) and one mole of water.
During the titration process, the reaction occurs gradually as the base is added to the acid solution.
The first end point of the titration is reached when the moles of HCl and NaOH are stoichiometrically equivalent, meaning they react in a 1:1 ratio. At this point, all the HCl has been neutralized by the NaOH, and no excess of either reagent remains.
However, if the titration is continued beyond the first end point, the reaction between HCl and NaOH can still occur, albeit in a different ratio.
The second end point refers to the point where the moles of NaOH added exceed the stoichiometrically required amount to neutralize the HCl completely. As a result, any excess NaOH added after the second end point reacts with the excess HCl in a 1:1 ratio.
Therefore, the median reaction at the second end point in the HCl and NaOH titration is:
HCl + NaOH → NaCl + H2O
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Taking the following information based on a catalytic reaction
Reaction Rate. [ Catalyst]
0.01428497 0.0001835590
0.00714248 0.0000847617
0.0000611800 0.00357124 0.0000238200 0.00178388 The order of the reaction based n the catalyst is Select one: a. 0.93 b. 1.00 C. 2.0 d. 2.1 e. 0.90 O f. 1.1 g. 1.5
The process of catalysis which involves adding a catalyst to a chemical reaction, increases the rate of the reaction.
Thus, Catalysts are not destroyed during the reaction and are unaffected by it. Very tiny amounts of catalyst are frequently sufficient when the reaction is swift and the catalyst recycles quickly; mixing, surface area, and temperature are key factors in reaction rate.
In order to regenerate the catalyst, it usually reacts with one or more reactants to produce intermediates that then give off the ultimate reaction product.
Homogeneous catalysis, in which all of the components are dispersed in the same phase as the reactant (often a gas or liquid), and heterogeneous catalysis, in which the components are not.
Thus, The process of catalysis which involves adding a catalyst to a chemical reaction, increases the rate of the reaction.
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what is it called when you apply science and mathematics to real life problems
Answer:
I think S.T.E.M but i'm not 100% sure
Explanation: