What happens to the carbonyl peak in a ring as the size of the ring contracts?.

Answers

Answer 1

As the size of the ring contracts, the carbonyl peak in the ring shifts to higher frequencies. This is due to the decrease in ring size, which increases the ring strain and results in a more polarized carbonyl group.

Hence, the carbonyl bond becomes weaker and more polar, which shifts the peak to higher frequencies. This effect is known as ring strain and is caused by the distortion of the bond angles and bond lengths in the ring.

A carbonyl peak is a strong signal that appears in infrared spectra due to the presence of a carbonyl group in a molecule. The position and shape of the peak are influenced by various factors such as ring size, substitution, and conjugation. In general, the carbonyl peak is a good indicator of the functional group and molecular structure of a compound.

The answer to the given question is that the carbonyl peak in a ring shifts to higher frequencies as the size of the ring contracts.

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Answer 2

The size of a ring can influence the chemical shift and intensity of signals generated from the nucleus located in the ring. This is because the ring size determines the ring current and aromaticity of the molecule in question. The carbonyl peak is a common NMR signal observed in organic molecules.

The carbonyl carbon, C=O, is located next to an electronegative atom (O, N), which draws electron density away from the carbon atom and causes it to appear at a high frequency or up field region in the NMR spectrum. The size of the ring can influence the carbonyl peak in two ways; the first effect is the ring strain effect, which is observed when the ring size is reduced.

The ring strain effect causes an increase in the deshielding effect experienced by the carbonyl carbon, resulting in a chemical shift towards a lower frequency or downfield region in the NMR spectrum. As the ring size reduces, the carbonyl peak moves towards a lower frequency, indicating that the electronegative atoms near the carbonyl group are pulling electrons towards themselves.

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Related Questions

Plz help me !!! I don’t get it

Plz help me !!! I dont get it

Answers

Answer:

Its Simple

Explanation:

1 . Acid

2.Hydronium

3. Litmus paper

4. Hydroxyl

5. Acid ....... Reactions

3. Classify each as a physical property or a chemical
property.
a. Aluminum has a silvery color.
b. Gold has a density of 19 g/cm”.
c. Sodium ignites when dropped in water.
d. Water boils at 100°C
e. Silver tarnishes.
f. Mercury is a liquid at room temperature.

Answers

We can classify the following properties as:

a. Aluminum has a silvery color. Physical property. b. Gold has a density of 19 g/cm³. Physical property. c. Sodium ignites when dropped in water. Chemical property. d. Water boils at 100°C. Physical property. e. Silver tarnishes. Chemical property. f. Mercury is a liquid at room temperature. Physical property.

The properties of matter can be:

A physical property: a characteristic of a substance that can be observed or measured without changing the identity of the substance.  A chemical property: describes the ability of a substance to undergo a specific chemical change.

Classify each as a physical property or a chemical property.

a. Aluminum has a silvery color. Physical property. Aluminum doesn't change by observing its color. b. Gold has a density of 19 g/cm³. Physical property. Gold doesn't change by measuring its density. c. Sodium ignites when dropped in water. Chemical property. Sodium reacts with water to form sodium hydroxide and hydrogen. d. Water boils at 100°C. Physical property. Water changes from the liquid to the gaseous state, but it still is water. e. Silver tarnishes. Chemical property. Silver reacts with sulfur-containing compounds in the air to form silver sulfides. f. Mercury is a liquid at room temperature. Physical property. Mercury doesn't change by observing its state of aggregation.

We can classify the following properties as:

a. Aluminum has a silvery color. Physical property. b. Gold has a density of 19 g/cm³. Physical property. c. Sodium ignites when dropped in water. Chemical property. d. Water boils at 100°C. Physical property. e. Silver tarnishes. Chemical property. f. Mercury is a liquid at room temperature. Physical property.

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Where can you find a common homogenous mixture?

A salt
B coffee
C orange juice
D trail mix

Answers

Answer:

B. Coffee

Explanation:

Coffee is a common homogenous mixture.

In lab, you calculate the density of an iron rod to be 7.30 g/cm3. The accepted value
for the density of iron is 7.80 g/cm3. What is your percent error?

Answers

Answer:

6.41 %

Explanation:

The percentage error of a certain measurement can be found by using the formula

\(P(\%) = \frac{error}{actual \: \: number} \times 100\% \\ \)

From the question

actual density = 7.80 g/cm³

error = 7.30 - 7.80 = 0.5

We have

\(p(\%) = \frac{0.5}{7.8} \times 100 \\ = 6.410256...\)

We have the final answer as

6.41 %

Hope this helps you

a 20.0ml sample of a 0.10 m solution of agno3 needs to have the silver ions precipitated out. how many ml of 0.10 m solution of bacl2 would need to be used to precipate out all the silver as agcl?

Answers

You would need 0.002 mol / 0.10 mol/L = 0.020 L = 20.0 ml of the 0.10 m solution of BaCl2 to precipitate out all the silver as AgCl.

To precipitate all the silver ions as AgCl, you need to determine the stoichiometric ratio between AgNO3 and BaCl2. The balanced equation for the reaction is

AgNO3 + BaCl2 -> AgCl + Ba(NO3)2.

The stoichiometric ratio between AgNO3 and AgCl is 1:1.

Therefore, the number of moles of AgNO3 in the 20.0 ml sample is 0.10 mol/L x 0.020 L

= 0.002 mol.

Since the stoichiometric ratio is 1:1, you would need an equal number of moles of BaCl2 to precipitate all the silver ions. The concentration of BaCl2 is also 0.10 mol/L.

Therefore, you would need 0.002 mol / 0.10 mol/L = 0.020 L = 20.0 ml of the 0.10 m solution of BaCl2 to precipitate out all the silver as AgCl.

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A solid solution with the composition NixMg1-x(NH4)2 (SO4)2*6H2O is analyzed and found to contain 11.58% Ni by weight. Find the value of x, retaining the proper number of significant figure. Note that x is a fraction

Answers

The value of x in the solid solution NixMg1-x(NH4)2(SO4)2*6H2O is 0.25.

To find the value of x, we use the given composition of the solid solution, which is 11.58% Ni by weight. This means that in 100 grams of the solid solution, 11.58 grams are Ni.

We can set up the equation:

(11.58 g Ni / 100 g of the solid solution) = x * (molar mass of Ni / molar mass of NixMg1-x(NH4)2(SO4)2*6H2O)

To solve for x, we need to know the molar masses of Ni and NixMg1-x(NH4)2(SO4)2*6H2O. Since we don't have that information, we can assume that the molar mass of Ni is approximately equal to its atomic mass (58.69 g/mol).

By rearranging the equation and plugging in the values, we can solve for x:

x = (11.58 g Ni / 100 g of the solid solution) * (molar mass of NixMg1-x(NH4)2(SO4)2*6H2O / molar mass of Ni)

The exact value of x will depend on the molar mass of NixMg1-x(NH4)2(SO4)2*6H2O, which is not provided. Therefore, we cannot determine the precise value of x, but based on the given data, x is approximately 0.25.

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What is the product of reductior of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes? A Ethyl 4-hydroxybutanoate B 1,4-Butanediol C 4-Hydroxybutanal D Ethyl butanoate

Answers

The product of the reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is Ethyl 4-hydroxybutanoate (Option A).

What is ethyl 4-oxobutanoate and what does it look like?

Ethyl 4-oxobutanoate, also known as ethyl acetoacetate, is an organic compound with the chemical formula CH₃C(O)CH₂CO₂C₂H₅. It is derived from acetoacetic acid and is an ester of acetoacetic acid.

Ethyl 4-oxobutanoate is a colorless liquid with a fruity odor.

During the reduction reaction, sodium borohydride (NaBH₄) acts as a reducing agent, donating hydride ions (H-) to the carbonyl group of the ethyl 4-oxobutanoate. This results in the conversion of the carbonyl group (C=O) to a hydroxyl group (OH) and the formation of the corresponding alcohol.

Therefore, the correct product of the reduction of ethyl 4-oxobutanoate with sodium borohydride is Ethyl 4-hydroxybutanoate (Option A).

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A student forgot to remove their silica gel beads before distillation of ester product. After distillation, his product was cloudy, indicating it was wet. Why

Answers

The presence of silica gel beads in the ester distillation process can result in a cloudy and wet product. This occurs because silica gel beads are hygroscopic and can absorb moisture from the surroundings, including the ester product, leading to the formation of water droplets.

Silica gel beads are commonly used as a desiccant due to their ability to absorb and hold moisture. They have a high affinity for water molecules and can quickly adsorb water vapor from the surrounding environment. In the case of the student's distillation process, if the silica gel beads were accidentally left in the system, they could have absorbed moisture during the distillation.

During the distillation process, the temperature increases, causing the ester product to evaporate and condense. However, if silica gel beads are present, they can act as a source of moisture. As the ester vapor condenses, it comes into contact with the silica gel beads, and the beads release the absorbed moisture. This leads to the formation of water droplets in the ester product, resulting in a cloudy and wet appearance.

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How does the mass of each atom compare to the average atomic mass of the
element given in the periodic table? *

Answers

The mass given in the periodic table is a weighted average of all isotopes of an element. For example Hydrogen is normally just one proton so one would expect its atomic mass to be exactly 1, but there are other naturally occurring isotopes of H (deuterium with a mass of 2 and tritium with a mass of 3)  that have more neutrons resulting in a weighted average slightly greater than 1.

The mass of the atoms is given by the number of neutrons and protons. The mass of the atom and the average mass of the element looks a little different due to mass defect.

What is a mass defect?

The mass defect has been the difference in the mass and the average mass of the elemental atom. It has been the energy that binds the neutrons and the protons together in the nucleus. The mass and the average atomic mass differ slightly.

The mass of an individual atom differs from the average atomic mass as average atomic mass is the sum of the masses of the isotope of the elements. Isotopes have little difference in masses due to the number of neutrons. For example mass and average atomic mass of hydrogen differs.

Therefore, the mass and the average atomic mass differ.

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how many molecules are in 1.5 mole of glucose

Answers

Answer:

In one mole of glucose, there are

6.022×1023

individual glucose molecules

Explanation:

Flask is immersed in a large beaker of very hot water. At first, the level of the liquid in the tube falls, but after a short time it rises. Explain why the liquid level in the tube stops falling and starts to rise.

Answers

Answer:

Explanation:

When a flask is dipped in very hot water in a large beaker , the flask expands due to heat gain . As a result , level of water in tube fitted in flask goes down .

After some time , the water inside tube also become hot so it expands  . coefficient of volume expansion of water is more than coefficient of volume expansion of glass . Hence greater expansion takes place in the volume of water . It is due to this fact that water level in tube starts rising after some time of fall .

According to the law of mass conservation, which of the following may NEVER occur as a result of a chemical reaction? a.creation of new chemical species b.reaction of starting materials c.rearranged to form new substances d.reduction in total mass

Answers

According to the law of mass conservation, the reduction in total mass may NEVER occur as a result of a chemical reaction.

This law explains that the total mass of the reactants is always equal to the total mass of the products, meaning that during a chemical reaction, the atoms of the starting materials are rearranged to form new substances and no new chemical species are created or destroyed. Therefore, the mass of the reactants is always conserved and remains constant throughout the reaction.

This law states that the total mass of the reactants must be equal to the total mass of the products in a closed system. So, while new chemical species may be created, starting materials may react, and substances may be rearranged, the overall mass must remain constant throughout the reaction.

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Consider the following reversible reaction. Upper C upper O (g) plus 2 upper H subscript 2 (g) double-headed arrow upper C upper H subscript 3 upper O upper H (g). What is the equilibrium constant expression for the given system?

Answers

Answer:

Answer:K subscript e q equals StartFraction StartBracket upper C upper O subscript 2 EndBracket StartBracket upper C a upper O EndBracket over StartBracket upper C a upper C upper O subscript 3 EndBracket EndFraction

Explanation: the answer has it's root in Law of mass action which states that; the rate of a chemical reaction is directly proportional to the product of the concentrations of the reactants raised to their respective stoichiometric coefficients.

The equilibrium constant expression for the given system of reaction is \(K_c = \frac{ [CH_3OH]}{ [CO][H_2]^2}\)

What is an equilibrium constant?

An equilibrium constant can be defined as an expression that shows the relationship between the reactants and products of a chemical reaction that is at equilibrium with respect to a specific unit.

Mathematically, the equilibrium constant is given by this formula:

\(K_c = \frac{ [C]^c[D]^d}{ [A]^a[B]^b}\)

Where:

A, B is the product.C, D is the reactant.

How to determine equilibrium constant.

First of all, we would write the properly balanced chemical equation with the phase for this system of chemical reaction:

                         CO(g) + 2H₂(g) ⇆ CH₃OH(g)  

Substituting the parameters into the formula, we have;

\(K_c = \frac{ [CH_3OH]}{ [CO][H_2]^2}\)

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2. A clear, colorless liquid is mixed with a clear, blue liquid resulting in a white powder suspended in a clear,
colorless liquid. Has a chemical reaction occurred? Why or why not?​

Answers

Answer:

Yes, a chemical reaction has occurred

Explanation:

A chemical change is known to lead to the appearance of a new substance. Another name for chemical change is chemical reaction.

The new substance is formed when the bonds in the reactants are being rearranged to yield the products of the reaction.

In this case, two clear liquids were mixed and the contents of the system interacted briefly to yield a new product which appears as the white powder suspended in a clear,  colorless liquid.

Don’t delete comment or I’ll report

Dont delete comment or Ill report

Answers

Answer:

The molar mass of O is 16 g/mol and since we have 2 oxygen molecules we multiply 16 g/mol to get 32 g/mol.  Therefore our best option would be option C, 32 g/mol.

Describe the evidence of a geologic process that you observed.

Answers

Answer:

what did i observe?

Explanation:

A chemical equilibrium between gaseous reactants and products is shown. N2(g) + 3H2(g) ⇌ 2NH3(g) How will the reaction be affected if the pressure on the system is decreased?

Answers

Answer:

reaction goes backward

as pressure decreases reaction shifts to more no of moles side that is 4 moles on left side

what trend does the first ionization energy follow, going down the periodic table?

Answers

Answer:

going down the periodic table atomic size increases,electronegativity and ionization decreases going down

Surprisingly, dipole-diple is not the predominant intermolecular force between ibr molecules in liquid ibr. Based on this information, what must be the main imf for ibr?.

Answers

Dipoles are not the dominant intermolecular forces between IBr molecules in liquids. IBr is a covalent bond.

A covalent bond is a chemical bond that requires the sharing of electrons to form electron pairs between atoms. The constant balance between attractive and repulsive forces between atoms according to their share of electrons is called a covalent bond.

Covalent bonds are much more common in natural chemistry than ionic bonds. A covalent bond is the simultaneous attraction of the nucleus to one or more electron pairs. Covalent compounds generally have low boiling and melting factors and are determined in all three body states at room temperature. Covalent bonds no longer conduct electricity; This is because covalent compounds no longer have charged particles that can carry electrons.

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Antarctica is a frozen land so cold and I see no changes in Wheeler scientist have discovered fossils

Answers

Answer:

The correct answer is - due to the movement of plates it is relocated.

Explanation:

Antarctica is a very cold part of the earth, it is so cold that there is no growth of trees or such vegetation. Even though there are no or less vegetation scientists found fossils of the trees.

It is relocated from the north where the conditions were warmer and easy for tree growth. It is then moved due to plate movements to the south pole. This is the reason behind the fossils scientist found.

a mixture is created with 5 grams of sugar, 5 grams of salt, and 4,000 cubic centimeters of water. which is the solvent?

Answers

In the mixture created with 5 grams of sugar, 5 grams of salt, and 4,000 cubic centimeters of water, the solvent is water.

A solvent is a substance that dissolves other substances to form a solution. In this case, water is the solvent because it is the substance that dissolves the sugar and salt to create the solution. The sugar and salt are the solutes, which are substances that are dissolved in a solvent to create a solution. In this mixture, water is the most abundant component, making up 4,000 cubic centimeters of the total volume, whereas sugar and salt only make up 5 grams each, so water is the solvent.

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Looking at the chemical reactions in each answer choice, please choose the chemical reaction that is balanced. A. Pb(OH)2 + 2HCl → 2H2O + PbCl2 B. 2Pb(OH)2 + HCl → H2O + 2PbCl2

Answers

Answer:

A. Pb(OH)2 + 2HCl → 2H2O + PbCl2

Explanation:

In a balanced reaction, the amount of different atoms in the products must be equal to number of atoms in reactants. With the equations of the problem:

A. Pb(OH)2 + 2HCl → 2H2O + PbCl2

There is 1 atom of Pb in reactants and products.

2 atoms of O in both sides.

4 atoms of H

And 2 atoms of Cl

That means this reaction is balanced

B. 2Pb(OH)2 + HCl → H2O + 2PbCl2

2 atoms of Pb

4 atoms of O in reactants but just 1 in products.

As the amount of oxygen is not equal for reactants and products we can say the reaction is unbalanced.

And right choice is A.

the pKa of 2-cyano-1,3-dithiane is?

Answers

The pKa of 2-cyano-1,3-dithiane is dependent on the specific functional groups and substituents present on the molecule. However, in general, dithianes are known to have acidic protons with pKa values ranging from 5-7.

The presence of a cyano group in 2-cyano-1,3-dithiane may increase the acidity of the molecule, resulting in a lower pKa value. The exact value of the pKa for this specific compound may be found through experimental measurements or calculated using computational methods.

The pKa of a compound is a measure of its acidity, specifically, the negative logarithm of the acid dissociation constant (Ka). In the case of 2-cyano-1,3-dithiane, this compound contains a dithiane functional group, which consists of a six-membered ring containing two sulfur atoms and four carbon atoms. The 2-cyano-1,3-dithiane derivative has an additional cyano (CN) group attached to the second carbon of the ring.

It is important to note that 2-cyano-1,3-dithiane itself is not acidic, and therefore does not have a pKa value. However, the compound can act as a nucleophile in reactions, making it useful in various organic synthesis processes. In order to obtain a pKa value for a compound, it must have an acidic proton that can be donated to a base.

In summary, 2-cyano-1,3-dithiane does not have a pKa value, as it lacks an acidic proton. Instead, its properties as a nucleophile make it valuable in organic synthesis.

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what is the concentration of hydrogen ion, H+, present in a water sample if 100. ml of the sample requires 7.2 ml of 2.5 x 10 -3 M NaOH to be neutralized

Answers

Answer:  1.8x10^-4 M H+

Explanation:  The number of moles of NaOH added to the 100 ml soultion will be equal to the number of moles of H+ present in that solution.  

Moles NaOH in 7.2 ml of 2.5x10^-3 M NaOH

(2.5x10^-3 M NaOH) is the same as 2.5x10^-3 moles NaOH/liter

(2.5x10^-3 moles NaOH/liter)*(7.2 ml)*(1 liter/1000ml) = 1.8x10^-4 moles NaOH used to titrate 100 ml of the acid.  That means there was 1.8x10^-4 moles of H^+ in 100 ml.  

Concentration of H^+ = (1.8x10^-4 moles H)/0.100 l) = 1.8x10^-4 M H+

(pH of 3.74)

A gas occupies 1.56 L at 101.3kpa. What will be the volume of this gas if the pressure becomes
45.5kpa?

Answers

The volume of a gas that initial occupies 1.56 L at 101.3 KPa is 3.47L.

How to calculate volume of a gas?

The volume of a gas at a given pressure can be calculated using Boyle's law equation as follows:

P1V1 = P2V2

Where;

P1 = initial pressureV1 = initial volumeP2 = final pressureV2 = final volume

According to this question, a gas occupies 1.56 L at 101.3 kpa, the volume of this gas if the pressure becomes 45.5kpa can be calculated as follows:

101.3 × 1.56 = 45.5 × V2

158.028 = 45.5V2

V2 = 3.47L

Therefore, the volume of a gas that initial occupies 1.56 L at 101.3 KPa is 3.47L.

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equivalent massof sodium​

Answers

Answer:

Sodium

Formula : Na

Equivalent mass:23.0

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Provide the proper coefficients (including 1's) required to balance this reaction:C2H6(g) + O2(g)→→CO2(g) + H2O(g)

Answers

The balanced equation for the reaction is:

C₂H₆(g) + 7/2 O₂(g) → 2 CO₂(g) + 3 H₂O(g)

To balance the equation, we need to ensure that the number of atoms of each element is the same on both sides of the reaction. Starting with carbon, we have 2 carbon atoms on the left side from C₂H₆ and 2 carbon atoms on the right side from 2 CO₂, so carbon is balanced.

Moving on to hydrogen, we have 6 hydrogen atoms on the left side from C₂H₆ and 6 hydrogen atoms on the right side from 3 H₂O, so hydrogen is balanced as well. Finally, for oxygen, we have 7/2 oxygen atoms on the left side from O₂ and 4 oxygen atoms on the right side from 2 CO₂ and 3 H₂O. To balance oxygen, we multiply O₂ by 7/2 to obtain 7/2 O₂, which gives us 7 oxygen atoms on each side.

Thus, the balanced equation is:

C₂H₆(g) + 7/2 O₂(g) → 2 CO₂(g) + 3 H₂O(g)

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PLEASE HELPPPP!!
Lab Report
Motion and Forces

Introduction-
1. What was the purpose of the experiment?

2. What were the independent, dependent, and control variables in your investigation? Describe the variables for each part of the experiment.

3. Write a hypothesis based on observations and scientific principles.

Experimental Methods-
4. What tools did you use to collect your data?

5. Write your procedure. List each step so that another student could follow the procedure and repeat your experiment.

Data and Observations-
6. Record your observations.

Conclusions-
7. What conclusions can you draw about how the sum of forces acting on an object affect its motion? Write an evidence-based claim.

8. Which mass, A, B, or C, was the greatest? Use the observations from your experiment and your knowledge of Newton’s laws of motion to write an evidence-based claim.


9. Make a model that shows the forces acting on two blocks on a flat, frictionless surface:
A 1 N block at rest
A 1 N block with 2 N of force applied in one horizontal direction
Include arrows to represent the forces and labels to indicate the magnitude of each force. Use your model to compare and explain the motion of each block.

Answers

Answer:

The purpose of this experiment was to see how motion takes place as well as Force The independent was the second item used I think that what happened at the thing I used I took a ball and threw it on the ground from height distance I recorded the time Same height

In one to two sentences, explain how to compare the strength of electrostatic forces between molecules in salt water to the strength of electrostatic forces between molecules in freshwater. Include a description of the data to be collected and how that data would allow one to draw conclusions about the relative strengths of the electrostatic forces in the two substances.

Answers

The boiling point of salt water is greater than that of fresh water hence the electrostatic forces between molecules in salt water is greater than that between the molecules in salt water.

Fresh water contains does not contain dissolved solutes like salt water. Salt water contains a lot of dissolved mineral salts making the salt water to be rich in ions.

Generally, the boiling points of substances can serve as a measure of the strength of electrostatic forces between molecules in either kind of water. We will easily find the that the boiling point of salt water is far higher than that of fresh water indicating greater electrostatic forces between molecules in salt water than between molecules in fresh water.

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if a car collides with a barrier and hit with a hundred 50 Newtons of force how much force does the barrier put in the car?​

Answers

Answer: 50 Newtons

Explanation:

Due to newtons third law of motion for every action there is an equal and opposite reaction or in this case the equal and opposite amount of force applied so the same 50 N is applied on the car by the barrier

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