what are the sources of error of electroplating?​

Answers

Answer 1

Answer:

electroplating is host to several defects due to the complexity of the process. Common electroplating defects often include issues that are present before plating, such as cold shuts, pitting, sharp edges, cleavage points and unclean manufacturing. During plating, flaking or a loss of adhesion can occur.

Explanation:


Related Questions

The meaning of the word symptom:​

Answers

The word "symptom" refers to a specific manifestation or indication of a condition, disease, or disorder that is experienced or observed by an individual.

Symptoms are subjective or objective changes in the body's normal functioning that may be recognized as abnormal, uncomfortable, or problematic. Symptoms can manifest in various ways depending on the nature of the underlying condition. They can be physical, such as pain, rash, cough, fever, or fatigue, indicating an illness or injury affecting the body. Symptoms can also be psychological, such as anxiety, depression, or confusion, reflecting disturbances in mental health.

Symptoms serve as important clues for medical professionals to identify and diagnose diseases or disorders. They provide valuable information about the nature, severity, and progression of an illness, helping healthcare providers formulate appropriate treatment plans. Additionally, symptoms may also be important for individuals to self-assess their own health status and seek appropriate medical attention.

It is essential to note that symptoms alone may not provide a definitive diagnosis, as they can overlap across different conditions. Further evaluation, including medical tests and examinations, is often necessary to confirm a diagnosis and determine the appropriate course of action.

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I need help please:(

I need help please:(

Answers

Diatomic: Composed of two atoms. Polar: A bond with a negative end and a positive end. Nonpolar: A bond in which neither atom takes more than its share of electrons. Metallic: A type of bond that allows valence electrons to move freely among ions. Electronegativity: Determines what type of bond will form.

The ability of an atom or functional group to draw electrons to itself is known as electronegativity in chemistry.

Diatomic molecules consist only of two atoms, whether they are from the same or distinct chemical elements.

Since charges fluctuate, a momentary dipole moment occurs in a so-called nonpolar molecule at any given time if the charge arrangement is spherically symmetric when averaged across time.

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A compound of P and F was analyzed as follows: heating 0.2324 g of the compound in a 378-cm3 container turned all of it to gas, which had a pressure of 97.3 mmHg at 77°C. Then the gas was mixed with calcium chloride solution, which turned all of the F to 0.2631 g of CaF2. Determine the molecular formula of the compound.

Answers

The molecular formula of the compound is determined as P₂F₄.

What is meant by molecular formula?

Molecular formula tells us which atoms and how many of each type of atom are present in the molecule.

Molar mass of CaF₂ is 78.07 g/mol(0.2631 g  CaF₂) × (1 mol  CaF₂ / 78.07 g  CaF₂) = 0.00337 mol  CaF₂

2F- + Ca₂+ →  CaF₂

(0.00337 mol  CaF₂) × (2 mol F / 1 mol  CaF₂) = 0.00674 mol F

As, Molar mass of F is 18.9984 g/mol

So, (0.00674 mol F) × (18.9984 g F / 1 mol F) = 0.12805 g F

1 mmHg = 0.00131578947 atm

(97.3 mmHg) × (0.00131578947 atm / 1 atm) = 0.128 atm

(378 cm³) × (1L / 1000 cm³) = 0.378 L

Now, T = 77 + 273 = 350 K

As, PV = nRT

n(PxFy) = PV / RT

n(PxFy) = (0.128 atm × 0.378 L) / (0.0821 L atm mol-1 K-1 × 350 K) = 0.001684 mol

n(PxFy) = 0.001684 mol

n(PxFy) = m(PxFy) / M(PxFy)

M(PxFy) = m(PxFy) / n(PxFy) = (0.2324 g) / (0.001684 mol) = 138 g/mol

m(PxFy) = m(P) + m(F)

0.2324 g = m(P) + 0.12805 g

m(P) = 0.2324 - 0.12805 = 0.10435

m(P) = 0.10435 g

Molar mass of P is 30.9737 g/mol

so, (0.10435 g P) × (1 mol P / 30.9737 g P) = 0.003369 mol P

Now, n(P) : n(F) = 0.003369 mol : 0.00674 mol = 1 : 2

Therefore, empirical formula of PxFy is PF₂

Molar mass of PF₂ 68.9705 g/mol

Molecular formula of PxFy is ( PF₂)n

n = M(PxFy) / M( PF₂) = (138) / (68.9705) = 2

Therefore, the molecular formula of PxFy is P₂F₄.

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Use bond energies to calculate ΔHrxn Δ H r x n for the reaction. 2H2(g)+O2(g)→2H2O(g) 2 H 2 ( g ) + O 2 ( g ) → 2 H 2 O ( g )

Use bond energies to calculate Hrxn H r x n for the reaction. 2H2(g)+O2(g)2H2O(g) 2 H 2 ( g ) + O 2 (

Answers

Answer:

\(\large \boxed{\text{-486 kJ}}\)

Explanation:

You calculate the energy required to break all the bonds in the reactants.

Then you subtract the energy needed to break all the bonds in the products.

                      2H₂   +   O₂ ⟶ 2H-O-H

Bonds:          2H-H    1O=O       4H-O

D/kJ·mol⁻¹:     436      498          464

\(\begin{array}{rcl}\Delta H & = & \sum{mD_{\text{reactants}}} - \sum{nD_{\text{products}}}\\& = & 2 \times 436 +1 \times 498 - 4 \times 464\\&=& 1370 - 1856\\&=&\textbf{-486 kJ}\\\end{array}\\\text{The enthalpy of reaction is $\large \boxed{\textbf{-486 kJ}}$}.\)

Which statement accurately describes how electrical power and current are related

Answers

Answer:

Electrical power is the product of voltage times current.

What is the volume of 0.960 moles of sulfur trioxide?

Answers

Answer:

76.86g

Explanation:

the molar mass of sulfur trioxide is about 80.06, so 80.06 grams per mol, 0.96*80.06=76.86g

cause and effect can you tell what problems are shown in each picutres?

Answers

The problem shown in picture 2 is a house damaged by wind and it is caused by the cutting down of trees that are suppose to serve as shield from wind (shown in picture 1)

How does trees shield buildings from heavy wind?

To shield buildings against raging winds effectively require tactful management of natural resources available nearby such as trees which can come in handy in many ways.

First off is using their leaves to reduce kinetic energy carried by strong gusts thanks to their innate capacity to disrupt airflow over an area; this lessens impact on structures positioned closely nearby.

Also worth noting is how tree trunks and branches help dampen wave motion while slowing down velocity at ground level- eventually reducing magnitude felt inside buildings during extreme weather events such as hurricanes or tornadoes Lastly ,roots provide much-needed support guaranteeing soil stability all year round - especially during windy seasons when soil displacement poses a significant threat to buildings around.

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The question lacks some details, see full details in the attached image.

cause and effect can you tell what problems are shown in each picutres?

The system at equilibrium below is heated.
How does the system adjust to reestablish
equilibrium?
2SO₂(g) + O₂(g) ⇒ 2SO3(g) + 198 kJ

Answers

When the system described above, which involves the reaction of sulfur dioxide (SO₂) and oxygen (O₂) to form sulfur trioxide (SO₃) with the release of 198 kJ of heat, is heated, it disrupts the equilibrium. In response to the increase in temperature, the system will adjust in order to reestablish equilibrium. Here's what happens:

According to Le Chatelier's principle, when a system at equilibrium is subjected to a stress, it will shift in a way that counteracts that stress. In this case, heating the system adds energy to it, which can be viewed as a stress. To counteract the increase in temperature, the system will shift in the endothermic direction, absorbing some of the added heat.

The forward reaction, in which SO₂ and O₂ combine to form SO₃, is an exothermic process since heat is released. By Le Chatelier's principle, increasing the temperature will shift the equilibrium to the left, favoring the reverse reaction (the endothermic direction). This means that some of the SO₃ molecules will decompose back into SO₂ and O₂.

As the system adjusts to reestablish equilibrium, the concentrations of SO₂, O₂, and SO₃ will change. The concentrations of SO₂ and O₂ will increase, while the concentration of SO₃ will decrease. This shift occurs in an attempt to consume some of the excess heat and reduce the temperature back towards the original equilibrium.

Overall, heating the system disrupts the equilibrium, causing a shift towards the reverse reaction. This shift helps absorb the added heat and restore the system to equilibrium by altering the concentrations of reactants and products.

What will happen when pressure on a reactant mixture at equilibrium and with fewer moles on the reactant side is increased

Answers

when pressure of the reactant mixture at the equilibrium and with the fewer moles in reactant side will be increased and the equilibrium will be shift to the side in the reaction where the fewer moles of the gas.

According to the Le Chartelier, when the reaction is in the equilibrium phase and the one of the constraints which will affect the rate of the reactions, and the equilibrium will be shift to the cancel out  this effect that the constraint had.

Therefore, If the pressure of the system or the reaction is in the equilibrium is change, the equilibrium of the reaction will be change that is depending on the side of the reaction with the highest number of the molecules.

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When potassium and chlorine form a chemical compound, the atoms

a. become less stable, and covalent bonds are
formed

b. become more stable, and covalent bonds are
formed

c. become less stable, and ionic bonds are
formed

d. become more stable, and ionic bonds are
formed

Answers

Answer:

D

Explanation:

Potassium metal and chlorine gas combine to form potassium chloride. The balanced equation is 2K (s) + Cl2 (g)→2KCl (s) There are two chlorine atoms on the left-hand side (LHS) and one chlorine atom on the right-hand side (RHS).

How should I write balanced net ionic equation for this reaction?
0.10 M Cu(NO3)2 + 0.010 M Cu(NO3)2
Because they're the same compound, I'm not sure how to write a net ionic equation for them. Any help is appreciated!

Answers

Answer:

Explanation:

Assumptions

They would ionize completely, or you must assume that.  The volumes must be the same as well.0.11M Cu(NO3)2 ===> 0.11MCu2+   + 0.22 NO3-

Note

The concentrations would merely add. All things change if the assumptions I've made are not true.

Determine the value of Kc for the following reaction, if the equilibrium concentrations are as follows: [N2]eq = 2.66 M, [H2]eq = 0.64 M, [NH3]eq = 3.34 M.

N2(g) + 3 H2(g) ⇌ 2 NH3(g)

Answers

The value of Kc for the given reaction is 0.0579 (rounded to four decimal places).

The formula for the equilibrium constant, Kc, of a reaction is given by the ratio of the product of the concentrations of the products raised to their respective stoichiometric coefficients to the product of the concentrations of the reactants raised to their respective stoichiometric coefficients.

The stoichiometric coefficients are the coefficients in the balanced chemical equation.

To determine the value of Kc for the reaction given by the following chemical equation:N2(g) + 3 H2(g) ⇌ 2 NH3(g)

we first need to write the expression for Kc.

The expression for Kc is given by the following formula:Kc = [NH3]² / [N2][H2]³.

We are given the equilibrium concentrations as follows:[N2]eq = 2.66 M[H2]eq = 0.64 M[NH3]eq = 3.34 M

We can substitute these values into the expression for Kc and obtain the following:Kc = (3.34)² / (2.66)(0.64)³ = 0.0579 (rounded to four decimal places).

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How many grams of solute are present in 835 mL of 0.390 M KBr?

Answers

The grams solutes ini 835 mL of 0.390 M KBr is 38.75 g.

The grams can be calculated as follows:

The first you should calculate the molar

Times the molar of KBr by its valume to get moles

n = Molar x volume

n = 0.390 M x 0.835L

n = 0.32565 moles

thus, you should calculate molar mass so you can calculate the gram

Mass of potasium = 39.10 g/mol

Mass of Bromine = 79.904 g/mol

mass molar = 39.1 g/mol+79.9 g/mol = 119 g/mol

The next step is calculate the gram by time the moles to  its mass molar

gram = n x mass molar

gram = 0.32565 moles x 119 g/mol= 38.75 g.

so, The grams solutes ini 835 mL of 0.390 M KBr is 38.75 g.

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Question 3Describe the energy in nuclear fuel and the way in witch it’s converted to electrical energy

Answers

The energy in nuclear fuel comes from the fission (splitting) or fusion (merging) of atomic nuclei. When the nucleus of an atom is split or merged, a large amount of energy is released in the form of heat and radiation. This energy is known as nuclear energy, and it is one of the most concentrated forms of energy known to us.

To convert nuclear energy into electrical energy, we typically use a nuclear reactor, which is a device that uses controlled nuclear reactions to generate heat. The heat is then used to produce steam, which drives a turbine connected to a generator. The generator converts the mechanical energy of the turbine into electrical energy, which can be distributed to homes and businesses through a power grid.

In more detail, the nuclear reactor contains fuel rods that are made of a radioactive material, such as uranium-235 or plutonium-239. When a neutron strikes the nucleus of one of these atoms, it causes the nucleus to split into two smaller nuclei, along with the release of additional neutrons and a large amount of heat. This process is known as nuclear fission, and it is sustained in the reactor by controlling the rate of neutron production and absorption.

The heat produced by nuclear fission is transferred to a coolant, such as water or gas, which carries the heat to a heat exchanger. In the heat ex

Think

about the physical properties used to identify elements as either metal,non-metals, or metalloids. Write

Imagine that you are asked to classify a group of elements as either metal, non-metals, or metalloids.

Explain how you would use their physical properties to accomplish this task.

Be sure to –Address the prompt, provide support, and conclude your thoughts. Write legibly and concisely.

Answers

Answer:

The elements can be classified as metals, nonmetals, or metalloids. ... Elements are further classified into metals, non-metals, and metalloids based on their properties, ... when they undergo chemical reactions They normally do not accept ... Most metal oxides are basic oxides and dissolve in water to form .

Explanation:

Each atom consists of a central nucleus and several shells that contain electrons. The outermost electrons are called valence electrons. Most atoms are stable with a configuration of eight valence electrons. This is known as the octet rule. How many valence electrons does each atom have?

Answers

If you are talking about an atom with a full octet, then it would just have a full shell of 8 valence electrons.

Answer:

valence

Explanation:

true/false. most chemicals can be cleaned up with a general spill kit, but a few chemicals require specialized spill procedures. for each substance listed, determine whether a general spill kit is sufficient or if a specialized spill kit is needed.

Answers

True, most chemicals can be cleaned up with a general spill kit, but a few chemicals require specialized spill procedures.

Weak chemicals can be cleaned up easily with general spill kits as they aren't corrosive enough to cause harm to living tissues and other non living materials such as marbles and construction units. Although, strong chemicals, like strong acids (such as hydrochloric acid, nitric acid) and strong bases are corrosive in nature, and need to be cleaned using specialised spill procedures for such chemicals. They can harm living tissues on contact and can degrade the quality of inanimate substances as well. Examples of some chemicals with what type of spill kit will be used for them:-

hydrofluoric acid = special

methanol = general

acetone = general

phosphoric acid = general

mercury = special

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Two asteroids are 75,000 m apart one has a mass of 8 x 10^7 N what is the mass of the other asteroid

Answers

The mass of the asteroid is C. 1.2 x \(10^{12}\) Kg

To find the mass of the other asteroid, we can rearrange the equation for the gravitational force between two objects:

F = (G * m1 * m2) / \(r^{2}\)

where F is the force of gravity, G is the gravitational constant, m1 and m2 are the masses of the two asteroids, and r is the distance between them.

Given that the distance between the asteroids is 75000 m, the force of gravity between them is 1.14 N, and one asteroid has a mass of 8 x \(10^{7}\) kg, we can substitute these values into the equation and solve for the mass of the other asteroid (m2):

1.14 N = (6.67430 × \(10^{-11}\) N \(m^{2}\)/\(Kg^{2}\) * 8 x \(10^{7}\) kg * \(m2\)) / \((75000 m)^{2}\)

Simplifying and solving the equation, we find that the mass of the other asteroid (m2) is approximately 1.2 x \(10^{12}\) kg. Therefore, Option C is correct.

The question was incomplete. find the full content below:

Two asteroids are 75000 m apart one has a mass of 8 x \(10^{7}\) kg if the force of gravity between them is 1.14 what is the mass of the asteroid

A. 3.4 x \(10^{11}\) kg

B. 8.3 x \(10^{12}\) kg

C. 1.2 x \(10^{12}\) kg

D. 1.2 x \(10^{10}\) kg

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When k2cr2o7 is cooled from 80oc to 20oc, how much solute will precipitate out of the solution?.

Answers

Approximately 90.6 g of K₂Cr₂O₇ would precipitate out of the solution when cooled from 80°C to 20°C.

What is the amount of solute that will precipitate?

To determine how much solute will precipitate out of a solution of potassium dichromate (K₂Cr₂O₇) when cooled from 80°C to 20°C, we apply the following method:

At 80°C:

Initial amount of K₂Cr₂O₇ = 100 g/L

At 20°C:

Solubility of K₂Cr₂O₇ = 9.4 g/L

Amount of K₂Cr₂O₇ that would remain in solution at 20°C = 9.4 g/L x 1 L = 9.4 g

Therefore, the amount of K₂Cr₂O₇ that would precipitate out of the solution when cooled from 80°C to 20°C would be:

Amount of K₂Cr₂O₇ that precipitates out = Initial amount - Amount that remains in solution at 20°C

Amount that precipitates out = 100 g - 9.4 g = 90.6 g

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The complete question is below:

When 100 g of k2cr2o7 in 1 liter of water is cooled from 80oc to 20oc, how much solute will precipitate out of the solution?.

A sample of 2.0 grams of helium gas is contained in a tank with a volume of 5.0 L at a temperature of 25° C. what is the pressure of the gas in the tank in atm?

Answers

To calculate the pressure of the helium gas in the tank, we can use the ideal gas law equation:

PV = nRT

where P is the pressure of the gas, V is the volume of the tank, n is the number of moles of the gas, R is the ideal gas constant, and T is the temperature of the gas in Kelvin.

First, we need to convert the temperature from Celsius to Kelvin by adding 273.15 to it:

T = 25°C + 273.15 = 298.15 K

Next, we need to calculate the number of moles of helium gas in the tank using its mass and molar mass:

n = m/M

where m is the mass of the gas and M is its molar mass. The molar mass of helium is approximately 4.00 g/mol.

n = 2.0 g / 4.00 g/mol = 0.50 mol

Now we can substitute the values we have into the ideal gas law equation and solve for P:

P = nRT/V

P = (0.50 mol)(0.08206 L·atm/(mol·K))(298.15 K)/(5.0 L)

P = 2.43 atm

Therefore, the pressure of the helium gas in the tank is approximately 2.43 atm.

what is the corrent name for CCl4?

Answers

The correct name for CCl4 Carbon tetrachloride.

CCl4 is assessed as a volatile natural compound. CCl4 is a clear, non-flammable, and heavy liquid that evaporates readily. Although CCl4 does not arise naturally, it's far ubiquitous because of industrial uses.

CCl4 consists of non-polar covalent bonds between carbon and chlorine. It has a molecular weight of 153.81 gms per mole, and a density of about 1.5867 gms per cubic centimeter. CCl4 also crystallizes in a monoclinic crystal lattice.

Carbon tetrachloride or CCl4 is used for:-

As a solvent withinside the rubber industry.As a cleansing agent withinside the dry cleaning industry.As a solvent withinside the chemical and drug industry.

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HELP ME PLEASE !!!

One time I went to the mountains. I was scared of altitude sickness, so I got cannisters of oxgen (O₂). These cannisters contain 2L of compressed oxygen (O₂). When the oxygen is pressurized, it condenses into its liquid form inside the cannister. How much would this oxygen (0₂) weigh in its liquid form?

2.9 grams
1.6 grams
3.6 grams
4.3 grams​​

Answers

According to the question,4.3 grams  would this oxygen (0₂) weigh in its liquid form.

What is the oxygen ?

Oxygen is an essential element for life. It is a colorless, odorless gas that makes up about 21% of the Earth's atmosphere. Oxygen is a vital component for the production of energy in all living things, as it is necessary for the process of respiration. Without oxygen, all living organisms would suffer, as their cells would not be able to produce the energy they need to survive. Oxygen is also necessary for the combustion of fuels, as it helps to create the conditions required for burning to occur. In addition, oxygen is used in many different industrial and scientific processes, ranging from welding to creating rocket fuel. Oxygen is incredibly important to life on Earth and is essential for the survival of all organisms.

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What does it mean if your hypothesis is wrong? What do you do?

Answers

Answer:

The purpose of a science experiment is to prove or deny a hypothesis. One's experiment is not a failure if the results do not match the hypothesis. When the data does not support the hypothesis, record it as though it did.

Answer:

when the findings do not aligh with the hypothesis

Assuming ideal solution behavior, what is the boiling point of a solution of 115.0 g of nonvolatile sucrose (table sugar), C₁₂H₂₂O₁₁ (342.300 g/mol), in 350.0 g of water (Kb = 0.512 °C m⁻¹; boiling point = 100.0 °C)?

a.)
100.00049 °C
b.)
99.5 °C
c.)
268.2 °C
d.)
100.5 °C

Answers

The boiling point of water is 100.0 °C, the boiling point of the solution will be : 101.49 °C.The correct answer is option (a) 100.00049 °C.

Ideal Solution : An ideal solution is a homogeneous mixture of two or more components that obeys Raoult's law, which states that each component's vapor pressure is proportional to its mole fraction.The boiling point of a solution depends on the solvent's properties and the solute's concentration. It's dependent on the mole fraction of the solvent and solute, as well as the total concentration of the solution. The change in boiling point of a solution is given byΔTb = Kb × m × i, whereKb = ebullioscopic constant, m molarity of the solution, and i = van't Hoff factor.Assuming that the solution's behavior is ideal, we may use the molality of the solution to compute the boiling point elevation of the solution.The molality of the solution is given by the following formula:m = (n₂ / m₂) ÷ (n₁ / m₁), where n is the number of moles, m is the mass, and the subscripts 1 and 2 refer to water and non-volatile solute sucrose, respectively.The molar mass of sucrose (C₁₂H₂₂O₁₁) is342.3 g/mol; therefore, the number of moles of sucrose is115.0 g ÷ 342.3 g/mol = 0.335 mol.m₁ = mass of water = 350.0 g, and m₂ = mass of sucrose = 115.0 g, as given in the problem.Therefore, the molality of the solution is given by:m = (0.335 mol / 0.115 kg) ÷ (1 mol / 1 kg) = 2.91 mol/kg.Substituting these values in the formula for ΔTb, we get:ΔTb = Kb × m = 0.512 °C m⁻¹ × 2.91 mol/kg = 1.49 °C.100.0 °C + 1.49 °C = 101.49 °C.

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Which of the following is NOT a natural resource? Check all that apply.

1. Air
2. Water
3. Plastic
4. Sunlight
5. Cotton
6. Glass
7. Coal
8. Copper

Answers

While being made from natural resources, electricity does not constitute a natural resource because it goes through several procedures to produce it.

What are the seven categories of natural resources?

Oil, coke, nat gas, metals, stone, or sand are examples of natural resources. Other natural resources include water, soil, sunlight, air, and so on. Natural resources have value because they enable life and provide for human needs.

A natural resource is land?

Financially referred to it as land and raw materials, land resources (also known as natural resources) are found naturally within ecosystems that are mostly unaltered by civilization. A natural resource's biodiversity levels across different habitats are frequently used to describe it.

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Question 5 of 10 Phosphorous is a nonmetal. Which property would you expect it to have? OA. It is a good conductor of heat. B. It is very shiny. C. It is a solid at room temperature. D. It is a gas at room temperature. SUBMIT D​

Answers

At ambient temperatures, it is a gas. A periodic table element is phosphorus. It belongs to group 15 of the periodic table and is categorised as a nonmetal.

It is well known that nonmetals differ from metals in both their physical and chemical characteristics. The right response is D. At ambient temperatures, it is a gas. At room temperature, nonmetals may exist in all three states of matter: liquid, gas, and solid.

With a boiling point of 44.2 °C, phosphorus is a nonmetal that is a gas at ambient temperature. It is neither highly glossy nor an excellent heat conductor.

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What is the difference between speed and average speed?

Answers

Answer: Speed is speed, or how fast something is going, while velocity is speed or how fast something is going in a specific direction. Average speed is the speeds added up and divided by number of speeds, and you do the same thing to calculate average velocity.

what is radiologist​

Answers

Radiologists are medical doctors that treat injuries using medical imaging (radiology)

Answer:

a person who uses X-rays or other high-energy radiation, especially a doctor specializing in radiology.

Explanation:

When a 20.2 mL sample of a 0.382 M aqueous hydrocyanic acid solution is titrated with a 0.421 M aqueous barium hydroxide solution, what is the pH after 13.7 mL of barium hydroxide have been added?

Answers

The concept molarity is used here to determine the pH after adding 12.6 mL of the base. The term molarity is an important method which is used to calculate the concentration of a solution. Here the pH is 1.23.

The term molarity is defined as the number of moles of the solute dissolved per litre of the solution. It is also called the molar concentration. It is represented as 'M' and its unit is mol / L.

Molarity is given as:

M = Number of moles / Volume of solution in liters

'n' of HCN = 20.2 × 1 L / 1000 mL × 0.382 = 0.0077 mol

'n' of Ba(OH)₂ = 13.7 × 1L / 1000 mL × 0.421 = 0.0057 mol

Excess H⁺ = 0.002

Total volume = 20.2 + 13.7 = 33.9 mL = 0.0339 L

Concentration of H⁺ = 0.002 / 0.0339 = 0.058

So pH is:

pH = - log[H⁺]

pH = - log[ 0.058] = 1.23

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The rotational spectrum of 79BrºF shows a series of equidistant lines spaced 0-714 33 cm - apart. Calculate the rotational constant B, and hence the moment of inertia and bond length of the molecule. Determine the wavenumber of the J = 9+= 10 transition, and find which transition gives rise to the most intense spectral line at room temperature (say 300 K).
and calculate the number of revolutions per second which the Brf molecule undergoes when in (a) the J = 0 state, (b) the J = 1 state, and (c) the J = 10 state. Hint: Use E = {lwin conjunction with Eqs (2.10) and (2.13), but remember that here w is in radians per second.[its Q season 2 from fundamentals of molcular spectruscopy . banwell.c.n]​

Answers

In the J = 0 state, the BrF molecule does not undergo any revolutions per second. In the J = 1 state, it undergoes approximately 0.498 revolutions per second, and in the J = 10 state, it undergoes approximately 15.71 revolutions per second.

To calculate the rotational constant B, we can use the formula:

B = 1 / (2 * π * Δν)

Where:

B = rotational constant

Δν = spacing between consecutive lines in the rotational spectrum

Given that the spacing between consecutive lines is 0.71433 cm^(-1), we can substitute this value into the formula:

B = 1 / (2 * π * 0.71433 cm^(-1))

B ≈ 0.079 cm^(-1)

The moment of inertia (I) of the molecule can be calculated using the formula:

I = h / (8 * π^2 * B)

Where:

h = Planck's constant

Given that the value of Planck's constant (h) is approximately 6.626 x 10^(-34) J·s, we can substitute the values into the formula:

I = (6.626 x 10^(-34) J·s) / (8 * π^2 * 0.079 cm^(-1))

I ≈ 2.11 x 10^(-46) kg·m^2

The bond length (r) of the molecule can be determined using the formula:

r = sqrt((h / (4 * π^2 * μ * B)) - r_e^2)

Where:

μ = reduced mass of the molecule

r_e = equilibrium bond length

To calculate the wavenumber (ν) of the J = 9+ to J = 10 transition, we can use the formula:

ν = 2 * B * (J + 1)

Substituting J = 9 into the formula, we get:

ν = 2 * 0.079 cm^(-1) * (9 + 1)

ν ≈ 1.58 cm^(-1)

To determine the most intense spectral line at room temperature (300 K), we can use the Boltzmann distribution law. The intensity (I) of a spectral line is proportional to the population of the corresponding rotational level:

I ∝ exp(-E / (k * T))

Where:

E = energy difference between the levels

k = Boltzmann constant

T = temperature in Kelvin

At room temperature (300 K), the population distribution decreases rapidly with increasing energy difference. Therefore, the transition with the lowest energy difference will have the most intense spectral line. In this case, the transition from J = 0 to J = 1 will have the most intense spectral line.

To calculate the number of revolutions per second, we can use the formula:

ω = 2 * π * B * J

Where:

ω = angular frequency (in radians per second)

J = rotational quantum number

For J = 0:

ω = 2 * π * 0.079 cm^(-1) * 0 = 0 rad/s

For J = 1:

ω = 2 * π * 0.079 cm^(-1) * 1 ≈ 0.498 rad/s

For J = 10:

ω = 2 * π * 0.079 cm^(-1) * 10 ≈ 15.71 rad/s

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