In the SN1 reaction of 2-chloro-2-methylpropane with water at different temperatures, the following reaction rate constants were obtained: 17°C, 0. 0052 s-1; 30°C, 0. 0202 s-1; 42°C, 0. 0608 s-1. Calculate the half-life of this reaction at 36°C. In seconds

Answers

Answer 1

The half-life of the reaction at 36°C is 19.2 seconds.

We can use the following equation to determine the  half-life of the reaction at 36°C;

\(t_{1/2}\) = ln(2) / k

where \(t_{1/2}\) is the half-life of the reaction and k is the reaction rate constant at the given temperature.

First, we need to find the reaction rate constant at 36°C. We can use the two rate constants given for 30°C and 42°C and the Arrhenius equation;

ln(k₂/k₁) = (-Ea/R) × (1/T₂ - 1/T₁)

where k₁ and k₂ are the rate constants at temperatures T₁ and T₂, Ea will be the activation energy, R is gas constant, and T is temperature in Kelvin.

We can choose 30°C (303 K) as T₁ and 42°C (315 K) as T₂, and solve for ln(k₂/k₁) to get;

ln(k₂/k₁) = (-Ea/R) × (1/T₂ - 1/T₁)

ln(0.0608/0.0202) = (-Ea/8.314 J/(mol×K)) × (1/315 K - 1/303 K)

Ea ≈ 52.7 kJ/mol

Next, we can use the Arrhenius equation to find the rate constant at 36°C (309 K);

k = A × exp(-Ea/RT)

k = 0.0202 s⁻¹ × exp(-52.7 kJ/mol / (8.314 J/(mol×K) × 309 K))

k ≈ 0.036 s⁻¹

Finally, we can use the half-life equation with this rate constant to find the half-life at 36°C;

\(t_{1/2}\)= ln(2) / k

\(t_{1/2}\) = ln(2) / 0.036 s⁻¹

\(t_{1/2}\) ≈ 19.2 s

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Related Questions

Please help any expert be sure your 100% correct please THANK YOU SO MUCH! ANY TEACHER PLEASE HELP!! THIS IS SCIENCE PLEASE EXPLAIN IT TO ME!!!

Answers

Ok of course I can help what is your question??

A 5g piece of aluminum foil (c=0.897) at 100°C is dropped into a 25g container of water (c=4.184) at 20°C. What is the final temperature of the aluminum? show work

Answers

Answer:

23.6°C

Explanation:

use delta h method

In three separate trials and under the same conditions, you measure a gas's density to be 2.865 kg/m^3, 2.852 kg/m^3, and 2.860 kg/m^3. the actual density of the gas is3.214 kg/m^3. evaluate the precision and accuracy of your measurement.

Answers

Out of given data, all data is close to actual value, so all are precise but only first data is very much close to actual value so it is accurate.

What is precision and accuracy?

When measuring data, precision and accuracy are two crucial considerations. Both precision and accuracy indicate how closely a measurement comes to the real value.

But accuracy also indicates how closely a measurement resembles a known or recognized value, while precision indicates how repeatable a measurement is, even if it is far from the acceptable value. Out of given data, all data is close to actual value, so all are precise but only first data is very much close to actual value so it is accurate.

Therefore, out of given data, all data is close to actual value, so all are precise but only first data is very much close to actual value so it is accurate.

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Question 116 g of sunflower oil is
used in a recipe. The density of the
oil is 0.925 g/mL. What is the volume
of the sunflower oil in mL?

Answers

Answer:  125.41 mL

Explanation:

Volume = mass ÷ density

             =  116 g  ÷  0.925 g/mL

             =  125.41 mL

A 116 g of sunflower oil of 0.925 g/mL has a volume of 125.41 mL.

Physical, Chemical, or Therapeutic Incompatibility?:
Antagonism between warfarin and phytonadione.

Answers

The incompatibility between warfarin and phytonadione is chemical, as they have opposite effects on blood clotting.

Warfarin is a blood thinner that inhibits the synthesis of vitamin K-dependent clotting factors, while phytonadione (also known as vitamin K1) is a clotting factor that reverses the effects of warfarin. However, this chemical incompatibility can have therapeutic benefits in certain situations, such as when a patient on warfarin experiences excessive bleeding and needs an antidote to reverse the blood-thinning effects.


The antagonism between warfarin and phytonadione represents a therapeutic incompatibility. Warfarin is an anticoagulant that works by inhibiting the synthesis of clotting factors, while phytonadione (vitamin K) is essential for the production of these factors. Thus, they have opposing effects in the body.

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an electron moved from a lower energy lever to a higher energy lever, and then back down again. What most likely happened

a. first heat was absorbed from the lower level to the higher level, and then a photon was released when the electron moved back
down
b. first heat was released from the lower level to the higher level, and then a photon was released when the electron moved back
down
c. first a photon was released when the electron moved from the lower level to the higher level, and then a photon was absorbed
when the electron moved back down
d. first a photon was absorbed when the electron moved from the lower level to the higher level, and then a photon was released
when the electron moved back down

Answers

Answer:

d

Explanation:

whats the lewis dot diagram for calcium

Answers

Draw the Lewis dot structure for each atom of the compound to show how many valence electrons are present in each atom. For example, the calcium atom in calcium chloride, CaCl2, has two valence electrons, and the chlorine atoms have seven valence electrons each.

whats the lewis dot diagram for calcium

The integumentary system functions to retain body fluids, protect against disease, eliminate waste products, and regulate body temperature. Which organelle performs the same function as the integumentary system?


Cell membrane

Mitochondria

Nucleus

Cell wall

Answers

I would go with the cell membrane In this case as the cell membrane is like skin

- Hope you can brainlest this answer

The integumentary system functions to retain body fluids, protect against disease, eliminate waste products, and regulate body temperature. Cell membrane performs the same function as the integumentary system. Therefore, option A is correct.

What is cell membrane?

The cell membrane performs a function that is similar to the integumentary system. The cell membrane is a thin, flexible layer that surrounds the cell and acts as a barrier between the cell and its external environment.

It helps to regulate the movement of substances in and out of the cell, maintain the balance of fluids and electrolytes, and protect the cell from harmful substances.

The cell membrane can also play a role in temperature regulation, as it helps to maintain the proper internal environment of the cell.

Thus, option A is correct.

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Question 9 of 10
Which functional group does the molecule below have?

Question 9 of 10Which functional group does the molecule below have?

Answers

Answer:

Hydroxyl

Explanation:

A P E X

I WILL GIVE BRAINLY PLS HELP

I WILL GIVE BRAINLY PLS HELP
I WILL GIVE BRAINLY PLS HELP

Answers

Answer:

Ice wedging

Explanation:

The rocks crack fill with water and then expand

How many atoms are in 2.5 moles of manganese?

Answers

Answer:

You use the fact that 1 mole of any substance contains exactly 6.022⋅1023 atoms or molecules of that substance - this is known as Avogadro's number. In your case, 1 mole of gold will have exactly 6.022⋅1023 atoms of gold.

Explanation:

Help me with these questions please!!

Help me with these questions please!!

Answers

Complete the table to show the fraction of a radioisotope left after each half-life has passed:

Number of half-lives 0 1 2 3 4 5 6

Fraction remaining 1 1/2 1/4 1/8 1/16 1/32 1/64

Use the table above to help you answer the questions below:

a) After 5 half-lives, the fraction remaining is 1/32 or 0.03125. To find the percentage remaining, multiply by 100:

0.03125 x 100 = 3.125%

Therefore, after 5 half-lives, 3.125% of the sample will remain.

b) After 4 half-lives, the fraction remaining is 1/16 or 0.0625.

c) To find out how many half-lives it will take for 25% of a sample to remain, you can set up an equation:

\((1/2)^{(n)} = 0.25\)

where n is the number of half-lives.

Taking the logarithm of both sides gives:

n x log(1/2) = log(0.25)

n = log(0.25) / log(1/2)

n = 2.

Therefore, it will take 2 half-lives for 25% of the sample to remain.

d) After 3 half-lives, the fraction remaining is 1/8 or 0.125. To find the percentage remaining, multiply by 100:

0.125 x 100 = 12.5%

Therefore, after 3 half-lives, 12.5% of the sample will remain.

e) The fraction remaining after 8 half-lives is \((1/2)^8\), which simplifies to 1/256.

The half-life of iodine-131 is 10 days.

After 30 days, three half-lives have passed:

\((1/2)^3 = 1/8\)

Therefore, after 30 days, 1/8 or 0.125 of the original mass will remain:

0.125 x 15g = 1.875g

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which of the following substance is usually one of the limiting amino acids in foods, particularly those of plant origin
a. Phenylalanine
b. Threonine
c. Methionine
d. Leucine

Answers

The substance that is usually one of the limiting amino acids in foods, particularly those of plant origin, can vary depending on the specific food. However, common limiting amino acids in plant-based foods include methionine and lysine. Therefore, option c, methionine, is likely the correct answer to your question.

Methionine (c) is usually one of the limiting amino acids in foods, particularly those of plant origin. Limiting amino acids are those that are present in the lowest quantity relative to the body's requirements, and they can limit the utilization of other amino acids in protein synthesis.

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What do you do to test a hypothesis
Guess
Create a spreadsheet with data
Publish a scientific paper
Design an experiment

Answers

create a spreadsheet with data

If you travel 152,758,000,000 cm' how many mº did you travel?

Answers

Answer:

1527580000 (I think if I did it right sorry if I didn't)

Explanation:

When converting cm to m. 1 centimeter is 0.01 Meters. That explanation probably doesn't help at all but I hope this is right and if not I do apologise!

How many seconds are required to produce 8.00 g of aluminum metal from the electrolysis ofmolten AlCl3 with an electrical current of 15.0 A

Answers

It would take approximately 108,800 seconds to produce 8.00 g of aluminum metal from the electrolysis of molten AlCl₃ with an electrical current of 15.0 A.

To calculate the time required, we need to use Faraday's law, which states that the amount of substance produced by an electrolysis reaction is directly proportional to the amount of charge that passes through the cell. The equation for Faraday's law is:

moles of substance = (electric charge) / (Faraday's constant)

where the Faraday's constant is the amount of electric charge per mole of electrons, and its value is 9.6485 x 10⁴ C/mol.

We can use the molar mass of aluminum (26.98 g/mol) to convert the moles of aluminum produced to grams. We can also use the current (I) and time (t) to calculate the amount of electric charge (Q) that passes through the cell, using the equation:

Q = It

Putting it all together, we get:

moles of Al = (It) / (Faraday's constant)

grams of Al = (moles of Al) x (molar mass of Al)

Solving for time (t), we get:

t = (grams of Al x Faraday's constant) / (molar mass of Al x I)

Plugging in the given values, we get:

t = (8.00 g x 9.6485 x 10⁴ C/mol) / (26.98 g/mol x 15.0 A) = 108,800 s

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Calculate the root mean square velocity for the atoms in a sample of helium gas at 25°C

Answers

The gas constant is equal to R=8.314 J/mol K, while the atomic mass of helium is equal to M=4.0 g/mol. M = 4.0 g / m o l . As a result, the helium atom's rms speed is 1304.7 m/s. So, 515 m/sec is the root-mean-square speed.

What is root mean square velocity?

The value of the square root of the sum of the squares of the stacking velocity values divided by the quantity of values is the root-mean square (RMS) velocity. The RMS velocity is the speed of a wave traveling along a certain ray path across subsurface strata with various interval velocities.

The expression v=sqrt(3RTM) and v=sqrt(3KTm), where R is the universal gas constant, T is the absolute (Kelvin) temperature, m is the molar mass, K is the Boltzmann's constant, and M is the molecular mass, gives the root mean square (R.M.S.) speed V of the molecules of an ideal gas.

Since the particles in a typical gas sample are flowing in all directions, the average velocity for that sample is zero, which is why we use the rms velocity instead of the average. This is an important formula since the particle velocity controls both the diffusion and effusion rates.

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An ion with 5 protons, 6 neutrons, and a charge of 3+ has an atomic number of
1. 5
2. 6
3. 8
4. 11

Answers

Answer:1. 5

Explanation: the element is boron and the atomic number is 5

water molecules are held to one another by....

Answers

Water molecules are held to one another by hydrogen bonding.

The oxygen atom has a slightly negative charge, and the hydrogen atoms have a slightly positive charge, making water molecules polar, or having an unequal distribution of electrons. This polarity enables a hydrogen bond to form between two neighboring water molecules by attracting the hydrogen atoms of one water molecule to the oxygen atom of the latter. Although each of these bonds is weak, they are strong enough to hold the molecules of water together, giving the water its cohesive qualities. Additionally, hydrogen bonding explains why water has a low surface tension and a high boiling temperature, and why ice floats on water.

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Convert 0.0134 Liter to millimeter

Answers

Answer:

13400 millimeters.

Explanation:

Multiply the volume value by 1e+6

Cell parts, what they look pike , and do

Answers

Answer:

All cells contain specialized, subcellular structures that are adapted to keep the cell alive. Some of these structures release energy, while others produce proteins, transport substances, and control cellular activities. Collectively, these structures are called organelles.Plant and animal cells both contain organelles, many of which are found in both types of cells. However, there are some organelles (such as chloroplasts, the cell wall, and large vacuoles) that are only found in plant cells.

Explanation:

hope this helps

draw the lewis structure for pf3cl2 in the window below and then answer the questions that follow.

Answers

The Lewis structure of PF3Cl2 consists of a central phosphorus atom bonded to three fluorine atoms and two chlorine atoms.

Lewis structures are used to visualize the bonding and electron distribution in molecules. They are based on the concept of valence electrons, which are the outermost electrons involved in chemical bonding. In the case of PF3Cl2, we determine the Lewis structure by considering the valence electrons of each atom.

To draw the Lewis structure for PF3Cl2, we need to consider the valence electrons of each element. Phosphorus (P) is in Group 5A and has 5 valence electrons. Fluorine (F) is in Group 7A and has 7 valence electrons, while chlorine (Cl) is in Group 7A and also has 7 valence electrons.

Starting with phosphorus, we place the central atom in the middle and surround it with the other atoms. We connect the phosphorus atom to three fluorine atoms (F) and two chlorine atoms (Cl) using single bonds. This arrangement ensures that each atom follows the octet rule, meaning they have a full valence shell of 8 electrons.

The Lewis structure for PF3Cl2 can be represented as follows:

  F

  |

Cl-P-Cl

  |

  F

In this structure, the central phosphorus (P) atom is bonded to three fluorine (F) atoms and two chlorine (Cl) atoms. Each bond is represented by a line, and lone pairs of electrons on each atom are not shown in this structure.

Overall, the Lewis structure provides a simplified representation of the molecular structure of PF3Cl2, allowing us to understand the arrangement of atoms and their bonding pattern.

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What is the order of steps in the synthesis of silver nanoparticles?

Answers

The synthesis of silver nanoparticles can involve various methods and conditions, but a general order of steps in a typical synthesis process might be as follows:

Preparation of the silver precursor: Silver nitrate (AgNO3) is commonly used as a silver precursor. It is dissolved in water or other suitable solvents to prepare a silver precursor solution.

Preparation of the reducing agent: A reducing agent, such as sodium borohydride (NaBH4) or sodium citrate, is prepared separately. The reducing agent will react with the silver precursor to form silver nanoparticles.

Mixing the silver precursor and reducing agent: The silver precursor solution and the reducing agent solution are mixed together under suitable conditions, such as controlled temperature and stirring, to allow the reduction reaction to occur.

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A student wants to prepare 250.0 mL of a 0.754 M HCl solution, starting with a 11.7 M HCl solution. How much of the 11.7 M HCl solution is needed

Answers

See answer in photo
A student wants to prepare 250.0 mL of a 0.754 M HCl solution, starting with a 11.7 M HCl solution. How

what happens to stars that are 8 times the sun's mass

Answers

Answer:

They forge heavy elements in their cores, explode as supernovas, and expel these elements into space.

Explanation:

Study the chemical reaction below and answer the questions that follow: 8Al + 3Fe₃O₄ → 4Al₂O₃ + 9Fe How many moles of iron would be produced if 4.0 moles of aluminum reacts with an excess of Fe₃O₄?

A. 4.0 moles
B. 4.5 moles
C. 8.0 moles
D. 9.0 moles

Answers

Answer: the answewr is A. hope this helps!

Explanation:

5.
Cr(NO3)3 (aq)
+
Ba (s)
Complete lonic:
I
Net lonic:

Answers

Answer:

Complete ionic: 2Cr(3+) + 6(NO3)- + 3Ba = 2Cr + 3Ba(2+) + 6(NO3)-

Net ionic; 2Cr(3+) + 3Ba = 2Cr + 3Ba(2+)

Explanation:

We are given;

Cr(NO3)3 (aq) + Ba (s)

Let's first find the product of this reaction before getting the complete and net ionic equations.

2Cr(NO3)3 + 3Ba = 2Cr + 3Ba(NO3)2

The complete ionic equation will be;

2Cr(3+) + 6(NO3)- + 3Ba = 2Cr + 3Ba(2+) + 6(NO3)-

The net ionic equation is gotten by eliminating the spectator ions from both left and right hand sides of the equation.

Thus, net ionic equation is;

2Cr(3+) + 3Ba = 2Cr + 3Ba(2+)

If a bottle of sunscreen containing 251 mL has 2. 0 % (m/v) avobenzone, how many grams of avobenzone are present

Answers

There are approximately 5.02 grams of avobenzone present in the bottle of sunscreen.

To determine the number of grams of avobenzone present in the sunscreen bottle, we need to use the mass/volume percentage (m/v) and the volume of the sunscreen.

Given:

Volume of sunscreen = 251 mL

Avobenzone concentration = 2.0% (m/v)

To find the mass of avobenzone, we can use the formula:

Mass = (Concentration × Volume) / 100

Plugging in the values:

Mass = (2.0 × 251) / 100

Mass = 5.02 grams

To calculate the mass of avobenzone, we would need information about the formulation of the sunscreen or the specific concentration or mass of avobenzone it contains. Once you provide that information, I will be able to assist you in calculating the grams of avobenzone present.

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How many oxygen atoms are there in 52. 06 g of carbon dioxide?.

Answers

To calculate the number of oxygen atoms in 52.06g of carbon dioxide, you will first need to determine the number of moles of carbon dioxide in the given mass, and then use the mole ratio between carbon dioxide and oxygen atoms to find the number of oxygen atoms.

Here's how to do it:

\text{moles of CO}_2=\frac{\text{mass of CO}_2}{\text{molar mass of CO}_2}

The molar mass of carbon dioxide (\text{CO}_2) is calculated by adding the atomic mass of carbon (12.01 g/mol) to two times the atomic mass of oxygen (2 x 16.00 g/mol) to get a molar mass of 44.01 g/mol.

Therefore,\text{moles of CO}_2=\frac{52.06\text{ g}}{44.01\text{ g/mol}}=1.182\text{ mol}

2. There are two oxygen atoms in each molecule of carbon dioxide, so for every 1 mole of \text{CO}_2 there are 2 moles of oxygen atoms.

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Assume you need to achieve a nitrogen concentration of 0.52 wt% at a position 5 mm into an iron-nitrogen alloy that initially contains 0.08 wt% N. The surface concentration is to be maintained at 1.00 wt% N, and the treatment is to be conducted at 1,100 K. (D. = 9.10E-05 m2/s and Qd = 168 kJ/mol) 25) Find the diffusion coefficient at 1,100 K if k=8.31 a) 8.91x10-12 m2/s b) 9.49x10-13 m²/s c) 7.44x10-11 m2/s d) 4.39x10-12 m2/s e) NoA

Answers

The diffusion coefficient is 4.39x10-12 m2/s.

Given information;

Initial nitrogen concentration, c₀ = 0.08 wt %

Nitrogen concentration to be achieved, cₙ = 0.52 wt %

Diffusion coefficient, D = 9.10E-05 m²/s

Temperature, T = 1100 K

Activation energy, Qd = 168 kJ/mol

Gas constant, R = 8.31 J/mol K

To find;

Diffusion coefficient at 1100 K using Arrhenius equation;

The Arrhenius equation for diffusion coefficient is given as;

D = D₀ exp(-Qd / R T)

where; D₀ is the diffusion coefficient at an infinite temperature.

Substituting the given values of D, Qd, R, and T into the equation above;

D = 9.10E-05 m²/s

Qd = 168 kJ/mol

R = 8.31 J/mol

KT = 1100 K

At 1100 K, the value of kT is;

kT = R T

     = 8.31 J/mol K x 1100 K

     = 9141 J/mol

Multiplying by Avogadro's number to get the value in J;

9141 J/mol x (6.022 x 10²³) / (1 mol) = 5.50 x 10²⁹ J-1

                                                          = 5.50 x 10²⁹ m²/kg

Multiplying by the Boltzmann constant to get the value in m²/s;

K = 1.38 x 10⁻²³ J/KD₀ can now be obtained by rearranging the Arrhenius equation as;

D₀ = D / exp(-Qd / R T)

Substituting the values into the equation;

D₀ = 9.10E-05 m²/s / exp(-168 x 10³ J/mol / 8.31 J/mol K x 1100 K)D₀

     = 9.10E-05 m²/s / exp(-21.36)D₀

     = 9.10E-05 m²/s / 1.29E-09D₀

     = 7.05E-04 m²/s

Therefore, the diffusion coefficient at 1,100 K if k = 8.31 is;

D = D₀ exp(-Qd / R T)D

   = 7.05E-04 m²/s exp(-Qd / R T)D

   = 7.05E-04 m²/s exp(-168 x 10³ J/mol / 8.31 J/mol K x 1100 K)

D = 7.05E-04 m²/s exp(-21.36)D

   = 4.39 x 10⁻¹² m²/s

Therefore, the correct option is 4.39x10-12 m2/s.

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