2. why snar reactions are not considered either sn1 or sn2: explain considering chlorobenzene as an example

Answers

Answer 1

SnAr (substitution nucleophilic aromatic) reactions are not considered either Sn1 or Sn2 because they include an aromatic ring and an electrophilic substitution mechanism.

This substitution is carried out by an intermediate complex. This reaction mechanism is specific to aromatic compounds and therefore does not fit into the classification of Sn1 or Sn2 reactions. In the SnAr mechanism, the leaving group is substituted by a nucleophile, which leads to the formation of a new bond.

Considering chlorobenzene as an example, the electrophilic substitution in SnAr reactions is carried out by chlorine (Cl), which makes the benzene ring electrophilic. The nucleophile replaces the Cl atom with an attacking atom.

The reaction can be defined as an SNAr mechanism that comprises a series of steps:

Attack of the nucleophile (Nu-) on the aromatic ring to form an intermediate complex. The intermediate complex is stabilized by the presence of an electron-withdrawing group (EWG) present on the ring. Chlorobenzene has an EWG in the form of chlorine (Cl) present on the ring. Displacement of the leaving group (LG) from the intermediate complex by the nucleophile.

Formation of the new carbon-nucleophile bond, resulting in the formation of the substituted product. The SNAr mechanism is unique to aromatic compounds and is not classified as Sn1 or Sn2 reactions.

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Related Questions

indicate which of the following statements is true (t) and which is false (f). a. benzoic acid forms a water-soluble salt, whereas naphthalene does not. b. naphthalene is more soluble in diethyl ether than is sodium benzoate. c. a criterion for a dry organic solution is that the solution is not cloudy. d. drying agents need not be removed prior to removing solvents when isolating products.

Answers

The following statements are true:

a. benzoic acid forms a water-soluble salt, whereas naphthalene does not.

b. naphthalene is more soluble in diethyl ether than is sodium benzoate. c. a criterion for a dry organic solution is that the solution is not cloudy.

and false is:

d. drying agents need not be removed prior to removing solvents when isolating products.

a. True (T): Benzoic acid is a carboxylic acid and can form water-soluble salts, such as sodium benzoate, through reaction with a base like sodium hydroxide. Naphthalene, on the other hand, is a nonpolar compound and does not readily form water-soluble salts.

b. True (T): Naphthalene is a nonpolar compound and is more soluble in nonpolar solvents like diethyl ether. Sodium benzoate, being a water-soluble salt, is more soluble in polar solvents like water.

c. True (T): A criterion for a dry organic solution is that it is not cloudy. Cloudiness in an organic solution can indicate the presence of water or other impurities.

d. False (F): Drying agents, such as silica gel or molecular sieves, are used to remove traces of water from organic solvents. However, they need to be removed prior to isolating the products because they can interfere with the purity and yield of the final product. Drying agents can adsorb the product or react with it, so it is important to remove them before further processing or analysis.

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give the number of valence electrons for alkali metals. express your answer as an integer.

Answers

Alkali metals have one valance electron.

Hope this helps. Brainliest is appreciated

1. 2KClO3 â 2KCl + 3O2How many grams of potassium chloride, KCl, are produced if 25.0g of potassium chlorate, KClO3, decompose?

Answers

15.2 g of KCl are produced when 25.0 g of KClO₃ decompose.

The balanced chemical equation is:

2KClO₃ → 2KCl + 3O₂

The molar mass of KClO₃ is 122.55 g/mol, and the molar mass of KCl is 74.55 g/mol.

To find the amount of KCl produced, we need to first determine the number of moles of KClO₃ decomposed.

Number of moles of KClO₃ = mass / molar mass = 25.0 g / 122.55 g/mol = 0.204 moles

From the balanced chemical equation, 2 moles of KClO₃ produce 2 moles of KCl.

Therefore, 0.204 moles of KClO₃ produce (2/2) × 0.204 moles of KCl = 0.204 moles of KCl.

The mass of KCl produced is given by:

Mass of KCl = number of moles × molar mass = 0.204 moles × 74.55 g/mol = 15.2 g

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where are the impurities located after the recrystallization?

Answers

The impure substance will crystallize in a purer form because the impurities won't crystallize eventually, therefore leaving the impurities behind in the solution.

Recrystallization is a considerably crucial technique for purifying nonvolatile organic solids. Recrystallization implicates dissolving the material to be purified in a relevant hot solvent. As the solvent cools, the solution evolves saturated with the solute and the solute crystallizes out. The compound is dissolved in the solvent, the solution is purified to deduct the insoluble impurities, and the solvent is evaporated to create the solid compound. The insoluble impurities are left behind in the filter paper.

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When zinc reacts with copper sulfate solution, zinc sulfate solution and copper are formed. (i) An experiment was carried out to measure the temperature change when zinc powder reactswith copper sulfate solution. Initial temperature of copper sulfate solution = 20 °Cfinal temperature of mixture after the reaction = 46 °CExplain what the temperature readings show about the type of heat change that occurs duringthis reaction

Answers

Answer:

it is an endothermic reaction

Explanation:

This is because there is a rise in temperature from 20 to 46. this means that the reaction takes in heat from the suuroundings

what is the density of a piece of aluminum foil that has a mass of 2.03g and the dimensions 0.0016 cm by 22.35 cm by 20.98 cm?

Answers

\(0.0016 * 22.35 * 20.98 = 0.75 cm^3\)

Density = 2.03/0.75 = 2.706 g/cm^3

How many atoms are present in a mole of CaCO3 ?
- 2 × Na atoms
- 5 × 6.022x10²³ atoms
- 2 × 6.022x10²³ atoms
- 5 × NA atom
Hey!! Can you say the answer ??

Answers

Answer:

5 x 6.022 x 10²³ atoms

Explanation:

There are 5 different atoms that make up a CaCO3 molecule, and since one mole of something is 6.022 x 10²³, there are 5 times that amount of atoms.

Intraspecific competition has a beneficial affect due to factors such as, ____________.

A. All of these
B. Predators
C. Disease
D. Over population

Answers

Intraspecific competition has a beneficial affect due to factors such as predators, disease and overpopulation. Thus option A is correct since all the above are beneficial factors.

What is intraspecific competition?

Competition is described as an interaction between two or more individuals from the same or two or more populations wherein one negatively impacts the other in access to a limited resource (or resources) (food, water, nesting places, shelter, mates, etc.). Intraspecific competition occurs when individuals from the same species (cospecifics) compete. The impact of competition on each individual within the species is determined by the sort of competition that occurs.  When a species competes for a finite resource, all individuals eat equal quantities until the supply is gone, all members of that population may die of starvation.  On the other hand, when one individual competes and wins over a resource, and that resource is exploited, it continues to exist.

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X :1s2 2s2 2p5. X là nguyên tố gì?

Answers

Answer:

Cấu hình điện tử của nguyên tố X là:

1s² 2s² 2p6 3s2 3p5

The electronic configuration of an element X is:

1s² 2s² 2p6 3s2 3p5

which one of the following mixtures in aqueous solution would be an effective buffer solution? hcooh and nahcoo hno2 and nano3 hclo4 and naclo4 hi and nai nh4cl and ch3nh2

Answers

The mixture of NH4Cl and CH3NH2 in aqueous solution would be an effective buffer solution.

How to determine the mixture that  would be an effective

The mixture of HCOOH and NaHCOO would be an effective buffer solution. The other options would not be effective buffer solutions because they either do not contain a weak acid and its conjugate base or the pKa values of the weak acid and its conjugate base are too far apart.

A buffer solution is a solution that resists a change in pH upon addition of small amounts of acid or base. The buffer capacity of a solution depends on the concentrations of the weak acid and its conjugate base. In this case, HCOOH (formic acid) is a weak acid and NaHCOO (sodium formate) is its conjugate base.

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I NEED OXIDATION AND REDUCED FOR BOTH ASAP PLS HELP (make sure its correct)

I NEED OXIDATION AND REDUCED FOR BOTH ASAP PLS HELP (make sure its correct)

Answers

Have you tried the app chem balancer I found it a great help when working on chemistry

1 of 20
0 0%
In what form (solid, liquid or gas) is crude
oil found?
Enter your answer​

Answers

Answer:

Gas

Explanation:

Because Crude oil can usually be found in the ground as a liquid and in the air is gas can be kerosene.

What the anode , cathode and the electrolyte of a cell tha t you might use to electrolyte a spoon made from iron with silver?​

Answers

The silver coating on the spoon is produced. When electrolyzing a spoon made from iron with silver, the anode, cathode, and electrolyte that can be used are as follows:

Anode: The anode is a negatively charged electrode, usually made of metal or graphite, that releases electrons during electrolysis. It is made of pure silver.Cathode: The cathode is a positively charged electrode that receives electrons during electrolysis. It is made of iron.Electrolyte: The electrolyte is a solution that conducts electricity and contains ions that can be reduced or oxidized. The electrolyte used for this process is a solution of silver nitrate (AgNO3) in water.The silver ion (Ag+) moves from the anode to the cathode through the electrolyte. At the cathode, it accepts an electron, reducing it to metallic silver (Ag). Fe(s) is oxidized to Fe2+(aq) ion at the anode, while Ag+ ions are reduced to Ag(s) at the cathode. Therefore, the silver coating on the spoon is produced.

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calculate the osmotic pressure of a 0.555 m solution of glucose at 32 °c.

Answers

The osmotic pressure of the 0.555 m solution of glucose at 32 °C is approximately 13.65 atm.

To calculate the osmotic pressure of a solution, you can use the formula:

Π = MRT

where:

Π is the osmotic pressure,

M is the molarity of the solution,

R is the ideal gas constant (0.0821 L·atm/(mol·K)),

T is the temperature in Kelvin.

First, let's convert the temperature from Celsius to Kelvin:

T = 32 °C + 273.15 = 305.15 K

Next, we can substitute the given values into the formula:

M = 0.555 mol/L

R = 0.0821 L·atm/(mol·K)

T = 305.15 K

Π = (0.555 mol/L) * (0.0821 L·atm/(mol·K)) * (305.15 K)

Π ≈ 13.65 atm

Therefore, the osmotic pressure of the 0.555 m solution of glucose at 32 °C is approximately 13.65 atm.

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an increase in enzyme or substrate concentration will

Answers

Answer: It will increase the rate of reaction

Explanation:

An increase in enzyme or substrate concentration will increase the rate of reaction.

What is an enzyme?

An enzyme is a biological catalyst and is almost always a protein. It speeds up the rate of a specific chemical reaction in the cell.

Initially, an increase in substrate concentration leads to an increase in the rate of an enzyme-catalyzed reaction. As the enzyme molecules become saturated with substrate, this increase in reaction rate levels off.

The rate of an enzyme-catalyzed reaction increases with an increase in the concentration of an enzyme.

Hence, an increase in enzyme or substrate concentration will increase the rate of reaction.

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what reaction (oxidation or reduction) occurs at the anode of a voltaic cell?

Answers

The reaction that occurs at the anode of a voltaic cell depends on the specific cell being used.

In general, however, the anode is the electrode where oxidation occurs, meaning that electrons are lost from the anode. This oxidation process is what creates the electrical potential difference that drives the flow of electrons through the cell and produces an electric current. On the other hand, reduction occurs at the cathode, which is the electrode where electrons are gained.

Together, the oxidation and reduction reactions that occur at the anode and cathode of a voltaic cell create a balanced redox reaction, which ultimately produces the flow of electricity that powers the cell.

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c) How many moles of ZnCl2 would be in 25 g?

Answers

Answer:

0.18 mol

Explanation:

n = m/M, where n is moles, m is mass of the sample, and M is molar mass.

M = 136.286 g/mol

m = 25 g

n = 25g/136.286g/mol

n = 0.18343777057 mol

n = 0.18 mol

Hope that helps

Considering the definition of molar mass, 0.1834 moles of ZnCl₂ would be in 25 g.

Definition of molar mass

The molar mass of substance is a property defined as its mass per unit quantity of substance, in other words, molar mass is the amount of mass that a substance contains in one mole.

The molar mass of a compound (also called Mass or Molecular Weight) is the sum of the molar mass of the elements that form it (whose value is found in the periodic table) multiplied by the number of times they appear in the compound.

Molar mass of ZnCl₂

In this case, you know the molar mass of the elements is:

Zn= 65.37 g/moleCl= 35.45 g/mole

So, the molar mass of the compound ZnCl₂ is calculated as:

ZnCl₂= 65.37 g/mole + 2× 35.45 g/mole

Solving:

ZnCl₂= 136.27 g/mole

Moles of 25 grams ZnCl₂

Next, you can apply the following rule of three: If by definition of molar mass 136.27 grams of the content are contained in 1 mole, 25 grams of the compound are contained in how many moles?

\(amount of moles=\frac{25 gramsx1 mole}{136.27 grams}\)

amount of moles= 0.1834 moles

Finally, 0.1834 moles of ZnCl₂ would be in 25 g.

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What is the formula of the compound vanadium(v) oxide? use the list of polyatomic ions and the periodic table to help you answer.

Answers

The formula of the compound vanadium (V) oxide is V2O5.

Ionic compound is formed by transfer of electrons from metal to non metal. For formation of a neutral ionic compound, the charges on cation and anion must be balanced. Ionic compounds are compounds with ionic bonds, given by the exchange of electrons between a cation (positive ion) and an anion (negative ion)The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.  Here vanadium is having an oxidation state of +5 and oxide is a ion with oxidation state of -2. Thus on exchange of their oxidation states, they combine to form neutral V2O5.

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1 Which climate zone has hot summers, cold winters, and average amounts of precipitation throughout the year? (2 points)

a
Equator

b
Polar

c
Temperate

d
Tropical

Answers

Answer:

C

Explanation:

i took the test

The temperate climatic zone has hot summers, cold winters, and average amounts of precipitation throughout the year. Thus, option C is correct.

What is a Climatic zone?

The climatic zone may be defined as a world area or part discerned from a neighbor by a significant physical climatic attribute that is of a transnational scale.

The movement of the sun from the tropic of cancer to the tropic of Capricorn determines the climate of a particular zone. The equator zone is more consistent with climatic attributes. The tropical zone has seasonal climatic attributes.  

Therefore, the correct option is C.

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homogeneous mixtures have ________ distribution.

Answers

Explanation: a homogeneous mixture forms when two or more substances are combined to make something uniform. In this type of mixture, the components must be evenly distributed troughout. Only one state of matter can be present and you can see individual ingredients.

My car has an internal volume of 12,000 L. If I drive my car into the river and it implodes, what will be the volume of the gas when the pressure goes from 1.0 atm to 1.4 atm?

Answers

The volume of gas when the pressure goes from 1.0 atm to 1.4 atm is 8,571.43 L.

When a car is driven into the river, it will implode due to the change in pressure. We are to calculate the volume of gas when the pressure goes from 1.0 atm to 1.4 atm if the internal volume of the car is 12,000 L.In order to solve the problem, we will use the combined gas law equation. The equation is given as follows;P1V1/T1 = P2V2/T2where P1 is the initial pressure, V1 is the initial volume, T1 is the initial temperature, P2 is the final pressure, V2 is the final volume, and T2 is the final temperature.We will assume that the initial temperature and final temperature are constant, and therefore, we can cancel them from the equation. Thus, the equation becomes;P1V1 = P2V2We can rearrange the equation to solve for V2 as follows;V2 = (P1V1)/P2Substituting the given values, we get;V2 = (1.0 atm * 12,000 L)/1.4 atmV2 = 8,571.43 L.

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Example The anticancer druge cir-platin hydrolysis in with constant 1. Solo - at pH 7:0 and 25°c. calculate the half life of the reaction

Answers

Answer:

ganda no beeeeeèeeeeee

draw the structure of the major organic products of the reaction. the starting material is a carbonyl bonded to a benzene ring and a methyl group. this reacts with excess b r 2 and excess o h minus.

Answers

Reaction 1: Addition of excess bromine (Br₂)

    _______Br________

   |                 |

C O + Br₂ --> C Br

|| || ||

Benzene Benzene ring

ring ring

The major organic product of the first reaction is a brominated carbonyl compound.

Reaction 2: Addition of excess hydroxide ions (OH⁻)

C Br + OH- --> C O⁻

|| || || ||

Benzene Benzene Benzene

ring ring ring

The major organic product of the second reaction is benzoic acid.

The reaction you described involves the addition of excess bromine (Br₂) and excess hydroxide ions (OH⁻) to a carbonyl compound bonded to a benzene ring and a methyl group. This reaction is known as the nucleophilic addition of bromine and subsequent hydrolysis. The major organic products obtained from this reaction are a brominated carbonyl compound and a benzoic acid. Here is the structure of the major organic products:

Starting material: Carbonyl compound bonded to a benzene ring and a methyl group

Reaction 1: Addition of excess bromine (Br₂)

    _______Br________

   |                 |

C O + Br₂ --> C Br

|| || ||

Benzene Benzene ring

ring ring

The major organic product of the first reaction is a brominated carbonyl compound. The carbonyl group gets brominated, resulting in the substitution of one of the carbonyl oxygen atoms with a bromine atom.

Reaction 2: Addition of excess hydroxide ions (OH⁻)

C Br + OH- --> C O-

|| || || ||

Benzene Benzene Benzene

ring ring ring

The major organic product of the second reaction is benzoic acid. The brominated carbonyl compound reacts with excess hydroxide ions, resulting in the hydrolysis of the carbonyl group and the formation of a carboxylic acid group (COOH) on the benzene ring.

Please note that the structures provided are simplified representations, and the exact arrangement of atoms and bonds may vary depending on the specific substituents and reaction conditions.

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1. The atomic number of lithium is 3. How many neutrons does an atom of lithium have fit is represented by the symbol shown below?
7
O A 2 neutrons
OB. 13 neutrons
O c. 4 neutrons
OD. 7 neutrons

Answers

Answer:

c)4 neutrons

Explanation:

The atomic mass of Lithium is 7.

we know,

atomic mass=no. of proton+ no. of neutron

So, no. of neutron = atomic mass - no. of proton=7-3=4

Note: Atomic number is the number of protons.

Hope, this helps you.

Consider the system 4NH3 (g) + 3O2 (g) —> 2N2 (g) + 6H2O + heat. How will the amount of N2 be affected by an addition of water vapor?

Answers

The addition of water vapor to the system will not directly affect the amount of N₂ produced in the given reaction.

The balanced equation shows that the production of N₂ is determined by the stoichiometry of the reactants, namely 4 moles of ammonia (NH₃) reacting with 3 moles of oxygen (O₂) to produce 2 moles of nitrogen gas (N₂). The presence of water vapor (H₂O) does not participate in the reaction as a reactant or a product. Therefore, the amount of N₂ formed will remain the same regardless of the presence or addition of water vapor.

However, it is worth noting that the addition of water vapor may indirectly affect the reaction by altering the conditions or equilibrium of the system. For example, the presence of water vapor could influence the reaction kinetics, the temperature, or the concentration of reactants. These factors could potentially impact the rate of the reaction or the position of the equilibrium, which might have an indirect effect on the final amount of N₂ produced. But without specific information about the conditions and the influence of water vapor, it cannot be determined how the amount of N₂ will be affected in this particular scenario.

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If 25 g of CH4 and 100 g of O2 react, what is the total mass of the reactants and products?

Answers

Answer:

125g

Explanation:

you simply add the masses together

what is the molecular weight of H2so4? ​

Answers

Lets find

\(\\ \sf\longmapsto H_2SO_4\)

\(\\ \sf\longmapsto 2(1u)+32u+4(16u)\)

\(\\ \sf\longmapsto 2u+32u+64u\)

\(\\ \sf\longmapsto 34u+64u\)

\(\\ \sf\longmapsto 98u\)

2. How much heat must be absorbed by a sample of 1337 grams (g) of ice at -10°C in order to turn it into water vapor at 120°C?​

Answers

Answer:

jk

Explanation:

what test would indicate a problem with carbohydrate metabolism kidney failure

Answers

One of the tests that can indicate a problem with carbohydrate metabolism in kidney failure is a blood glucose test. Kidney failure can lead to impaired glucose regulation, resulting in elevated blood glucose levels.

This test measures the concentration of glucose in the blood and can help identify abnormalities in carbohydrate metabolism. Kidney failure, also known as renal failure, can significantly impact the body's ability to regulate glucose levels. The kidneys play a crucial role in filtering waste products and maintaining the balance of various substances in the blood, including glucose. When the kidneys are impaired, they may struggle to efficiently process glucose, leading to elevated blood sugar levels. A blood glucose test is commonly used to assess the concentration of glucose in the bloodstream. This test involves drawing a blood sample and measuring the amount of glucose present. In individuals with kidney failure, the test may reveal high blood glucose levels, indicating a problem with carbohydrate metabolism. The elevated blood glucose levels in kidney failure can be attributed to several factors. The kidneys may have reduced insulin sensitivity or impaired insulin secretion, which are essential for proper glucose utilization. Additionally, the impaired filtration and reabsorption functions of the kidneys can lead to glucose being lost in the urine, further contributing to elevated blood glucose levels. Monitoring blood glucose levels in individuals with kidney failure is crucial as it helps guide treatment and management strategies. Controlling blood glucose levels through dietary modifications, medication, or insulin therapy may be necessary to prevent complications associated with uncontrolled diabetes.In conclusion, a blood glucose test is an important diagnostic tool to assess carbohydrate metabolism in individuals with kidney failure. Elevated blood glucose levels in this population indicate potential abnormalities in glucose regulation due to the impaired kidney function. Proper management of carbohydrate metabolism and blood glucose levels is essential for overall health and preventing complications associated with kidney failure.

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Answers

******************* ijustwantthepoints *************************

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